Effect of Copper Sulfate Concentration on the Electrochemical Nucleation Process, Growth and Properties of n-Type Cu2O Thin Films

Аннотация

Cu₂O-n thin films were successfully electrodeposited from a Cu(II) lactate solution containing different concentrations of copper(II) sulfate (CuSO₄) and 1 M lactic acid (C₃H₆O₃) at pH 6.5. The electrochemical behaviour of Cu₂O thin films has been investigated by means of cyclic voltammetry (CV), chronoamperometry (CA). The nucleation behaviour of the deposited Cu₂O has been studied on FTO substrates as a function of Cu²⁺ concentration. It was found that the nucleation changes from progressive to instantaneous with increasing Cu²⁺ concentration. Many electrochemical parameters were investigated such as transfer coefficient, diffusion coefficient, cathodic and anodic charges, nucleation rate etc. The effect of the nucleation mechanism on microstructural and optical properties of Cu₂O were investigated by X-ray diffractometry (XRD) and ultraviolet visible spectrophotometry (UV–Vis–NIR) and photoluminescence (PL). The optimal concentration of Cu²⁺ ions was found to be 0.075 and 0.1 M obtained with instantaneous nucleation process. The high photoluminescence (PL) efficiency observed indicating good optical properties with a high carrier density, small depletion layer, high photo-generated electron–hole pairs, narrow band gap and low charge transfer resistance. This results exhibit a high photoelectric performance.