Composition-Controllable AuPt Alloy Catalysts for Electrooxidation of Formic Acid
- Authors: Shen W.1, Sang J.1, Cai L.1, Li Y.1
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Affiliations:
- State Key Lab of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering
- Issue: Vol 54, No 11 (2018)
- Pages: 809-816
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/189534
- DOI: https://doi.org/10.1134/S1023193518110071
- ID: 189534
Cite item
Abstract
AuPt alloy catalysts with various compositions have been successfully prepared simply by one-step co-reduction of Au and Pt precursors involving sodium citrate as stabilizer and reductant. XRD, TEM and EDX element mapping analysis confirmed that the resulting AuPt nanoparticles are single-phase alloys rather than random mixtures of tiny Au and Pt particles. Compared with Pt/C, alloying Au with Pt can effectively alter the kinetic process of formic acid oxidation, reducing the generation of CO-like intermediates. Au81Pt19 displays superior electrocatalytic activity and durability, ~11 times in the mass activity better than commercial Pt/C and may be of practical significance for the commercialization of direct formic acid fuel cell.
About the authors
Wen-Jin Shen
State Key Lab of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering
Email: liyje@hnu.edu.cn
China, Changsha, 410082
Ji-Long Sang
State Key Lab of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering
Email: liyje@hnu.edu.cn
China, Changsha, 410082
Ling Cai
State Key Lab of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering
Email: liyje@hnu.edu.cn
China, Changsha, 410082
Yong-Jun Li
State Key Lab of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering
Author for correspondence.
Email: liyje@hnu.edu.cn
China, Changsha, 410082