Electric Conductivity of α-Al2O3 Suspensions in Carbonate and Carbonate-Chloride Melts


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Abstract

The temperature dependence of the specific electric conductivity of suspensions based on carbonate and carbonate-chloride melts immobilized with α-Al2O3 powder was studied. For carbonate-chloride melts immobilized with α-Al2O3, the decrease in the specific electric conductivity considerably exceeded the effect associated with a decrease in the volume fraction of charge carriers. The Raman spectroscopy and Xray diffraction analysis showed that there was no chemical interaction of α-Al2O3 with the carbonate and carbonate-chloride melt that could lead to the formation of additional nonconducting phases in these systems in the temperature range under study.

About the authors

E. V. Nikolaeva

Institute of High-Temperature Electrochemistry, Ural Branch; Ural Federal University named after the first President of Russia B.N. Yeltsin

Author for correspondence.
Email: nikolaeva@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002

I. D. Zakir’yanova

Institute of High-Temperature Electrochemistry, Ural Branch; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: nikolaeva@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002

A. L. Bove

Institute of High-Temperature Electrochemistry, Ural Branch; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: nikolaeva@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002


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