Effect of Parameters of Pulsed Potential Mode on Concentration Changes in the Bulk Loose Zinc Deposit and Its Properties


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Abstract

It is shown that the parameters of pulsed potential modes (pulse-on and pulse-off times) have a pronounced effect on the growth dynamics and properties of loose metal deposits in the cases that the process proceeds under the conditions of non-steady-state diffusion. It is proposed to use a ratio between the cathodic and anodic charges in a cycle as a parameter that characterizes the concentration changes. By varying the parameters of pulsed potential, zinc deposits of various morphology can be obtained: from compact deposits to highly porous deposits that consist of branched dendritic particles.

About the authors

V. S. Nikitin

Institute of Chemical Technology

Author for correspondence.
Email: nikitin-viachieslav@mail.ru
Russian Federation, Yekaterinburg, 620076

T. N. Ostanina

Institute of Chemical Technology

Email: nikitin-viachieslav@mail.ru
Russian Federation, Yekaterinburg, 620076

V. M. Rudoi

Institute of Chemical Technology

Email: nikitin-viachieslav@mail.ru
Russian Federation, Yekaterinburg, 620076


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