Oxygen Nonstoichiometry and Transport Properties of Mixed-Conducting Ce0.6–xLa0.4PrxO2–δ
- Authors: Ivanov A.I.1, Kolotygin V.A.1, Patrakeev M.V.2, Markov A.A.2, Bredikhin S.I.1, Kharton V.V.1
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Affiliations:
- Institute of Solid State Physics
- Institute of Solid State Chemistry, Ural Branch
- Issue: Vol 54, No 6 (2018)
- Pages: 486-492
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/189369
- DOI: https://doi.org/10.1134/S1023193518060058
- ID: 189369
Cite item
Abstract
The oxygen nonstoichiometry and electrical conductivity of fluorite-type solid solutions Ce0.6‒xLa0.4PrxO2–δ (x = 0.1–0.2) were studied in the oxygen partial pressure range 10–19–0.35 atm at 1023–1223 K. It was confirmed that the Pr4+/3+ and Ce4+/3+ redox pairs, which determine the concentration of p- and n-type electron charge carriers, play the dominant roles under oxidizing and reducing conditions, respectively. The conductivity vs. charge carrier concentration dependencies in these conditions are almost linear. Increasing praseodymium content leads to a substantially higher hole conductivity and an expanded range of the oxygen nonstoichiometry variations at high oxygen partial pressures. Under reducing conditions when praseodymium cations become trivalent opposite trends are observed on doping.
About the authors
A. I. Ivanov
Institute of Solid State Physics
Author for correspondence.
Email: aliv@issp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. A. Kolotygin
Institute of Solid State Physics
Email: aliv@issp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
M. V. Patrakeev
Institute of Solid State Chemistry, Ural Branch
Email: aliv@issp.ac.ru
Russian Federation, Yekaterinburg, 620990
A. A. Markov
Institute of Solid State Chemistry, Ural Branch
Email: aliv@issp.ac.ru
Russian Federation, Yekaterinburg, 620990
S. I. Bredikhin
Institute of Solid State Physics
Email: aliv@issp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. V. Kharton
Institute of Solid State Physics
Email: aliv@issp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432