Interpretation of the frequency transients accompanying the submersion of a polymer coated QCM quartz crystal in water
- Authors: Yoo H.Y.1, Bruckenstein S.1, Pater E.2
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Affiliations:
- Stanley Bruckenstein Chemical Consulting and Services
- State University of New York
- Issue: Vol 53, No 10 (2017)
- Pages: 1160-1164
- Section: Section 2. Physicochemical Mechanics
- URL: https://journals.rcsi.science/1023-1935/article/view/189084
- DOI: https://doi.org/10.1134/S1023193517100056
- ID: 189084
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Abstract
10 MHz QCM quartz crystals, uncoated or coated with films of PMMA and/or PEO, were rapidly submerged into aqueous medium. The changes in these crystals’ resonance frequencies were recorded. In all cases after a few seconds crystal’s resonant frequency became constant at a value that depended upon whether the crystal was polished or etched and whether it was coated or uncoated with a polymer film. A blended polymer film composed of PMMA and PEO, when coated on a QCM crystal and then submerged in water showed a rapid frequency increase corresponding to the removal (leaching) of PEO from the film and creating a porous PMMA film whose pores were filled with water. The porosity of the leached film was determined.
About the authors
Ho Yeon Yoo
Stanley Bruckenstein Chemical Consulting and Services
Email: chemstan@gmail.com
United States, Williamsville, NY
Stanley Bruckenstein
Stanley Bruckenstein Chemical Consulting and Services
Author for correspondence.
Email: chemstan@gmail.com
United States, Williamsville, NY
Ewa Pater
State University of New York
Email: chemstan@gmail.com
United States, Plattsburgh, NY