Electrochemical dehalogenation of polytrifluorochloroethylene

A. A. Stepanov; M. I. Buzin; E. G. Kononova; V. E. Sosenkin; Yu. M. Vol’fkovich

doi:10.1134/S1023193517050135

Electrochemical dehalogenation of polytrifluorochloroethylene

作者: Stepanov A.A.¹, Buzin M.I.¹, Kononova E.G.¹, Sosenkin V.E.², Vol’fkovich Y.M.²
隶属关系:
1. Nesmeyanov Institute of Organoelement Compounds
2. Frumkin Institute of Physical Chemistry and Electrochemistry
期: 卷 53, 编号 5 (2017)
页面: 555-559
栏目: Short Communications
URL: https://journals.rcsi.science/1023-1935/article/view/188742
DOI: https://doi.org/10.1134/S1023193517050135
ID: 188742

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The electrochemical reduction of polytrifluorochloroethylene suspended in an electrolyte using organic electron transfer mediators led to surface modification of the polymer. Pyrolysis of the reduction product was accompanied by the formation of a highly porous thermally stable polycarbon material with pore sizes in a very wide range, approximately from 1 to 10⁵ nm.