Email this article Electropolymerization of magnesium 5,15-di(n-methoxyphenyl)porphine
- Authors: Konev D.V.1,2, Lizgina K.V.3, Istakova O.I.1,2, Baulin V.E.4,5, Kalashnikova I.P.4,5, Devillers C.H.6, Vorotyntsev M.A.1,2,3,6
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Affiliations:
- Institute of Problems of Chemical Physics
- Mendeleev University of Chemical Technology
- Faculty of Chemistry
- Institute of Physiologically Active Compounds
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Molecular Chemistry of the University of Burgundy
- Issue: Vol 52, No 12 (2016)
- Pages: 1150-1158
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188304
- DOI: https://doi.org/10.1134/S1023193516120077
- ID: 188304
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Abstract
The process of electroxidative polymerization of magnesium 5,15-di(n-methoxyphenyl)porphine MgP(MeOPh)2 is studied. The presence of substituents in positions 5 and 15 of the porphine macroring makes reactive two of its four meso positions, which allows new bonds to be formed only in the opposite positions 10 and 20. As a result, the process of electropolymerization of this substituted monomer at its oxidation can produce only linear chains, in contrast to unsubstituted magnesium porphine MgP for which the polymer structure can both be linear and contain zigzag and/or cruciform fragments.
About the authors
D. V. Konev
Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology
Author for correspondence.
Email: dkfrvzh@gmail.com
Russian Federation, Chernogolovka, Moscow Oblast’, 142432; Moscow, 125047
K. V. Lizgina
Faculty of Chemistry
Email: dkfrvzh@gmail.com
Russian Federation, Leninskie Gory, Moscow, 119991
O. I. Istakova
Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology
Email: dkfrvzh@gmail.com
Russian Federation, Chernogolovka, Moscow Oblast’, 142432; Moscow, 125047
V. E. Baulin
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: dkfrvzh@gmail.com
Russian Federation, Chernogolovka, Moscow Oblast’, 142432; Moscow, 119991
I. P. Kalashnikova
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: dkfrvzh@gmail.com
Russian Federation, Chernogolovka, Moscow Oblast’, 142432; Moscow, 119991
C. H. Devillers
Institute of Molecular Chemistry of the University of Burgundy
Email: dkfrvzh@gmail.com
France, Dijon
M. A. Vorotyntsev
Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology; Faculty of Chemistry; Institute of Molecular Chemistry of the University of Burgundy
Email: dkfrvzh@gmail.com
Russian Federation, Chernogolovka, Moscow Oblast’, 142432; Moscow, 125047; Leninskie Gory, Moscow, 119991; Dijon
