电邮这篇文章 Electropolymerization of magnesium 5,15-di(n-methoxyphenyl)porphine
- 作者: Konev D.V.1,2, Lizgina K.V.3, Istakova O.I.1,2, Baulin V.E.4,5, Kalashnikova I.P.4,5, Devillers C.H.6, Vorotyntsev M.A.1,2,3,6
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隶属关系:
- Institute of Problems of Chemical Physics
- Mendeleev University of Chemical Technology
- Faculty of Chemistry
- Institute of Physiologically Active Compounds
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Molecular Chemistry of the University of Burgundy
- 期: 卷 52, 编号 12 (2016)
- 页面: 1150-1158
- 栏目: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188304
- DOI: https://doi.org/10.1134/S1023193516120077
- ID: 188304
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详细
The process of electroxidative polymerization of magnesium 5,15-di(n-methoxyphenyl)porphine MgP(MeOPh)2 is studied. The presence of substituents in positions 5 and 15 of the porphine macroring makes reactive two of its four meso positions, which allows new bonds to be formed only in the opposite positions 10 and 20. As a result, the process of electropolymerization of this substituted monomer at its oxidation can produce only linear chains, in contrast to unsubstituted magnesium porphine MgP for which the polymer structure can both be linear and contain zigzag and/or cruciform fragments.
作者简介
D. Konev
Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology
编辑信件的主要联系方式.
Email: dkfrvzh@gmail.com
俄罗斯联邦, Chernogolovka, Moscow Oblast’, 142432; Moscow, 125047
K. Lizgina
Faculty of Chemistry
Email: dkfrvzh@gmail.com
俄罗斯联邦, Leninskie Gory, Moscow, 119991
O. Istakova
Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology
Email: dkfrvzh@gmail.com
俄罗斯联邦, Chernogolovka, Moscow Oblast’, 142432; Moscow, 125047
V. Baulin
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: dkfrvzh@gmail.com
俄罗斯联邦, Chernogolovka, Moscow Oblast’, 142432; Moscow, 119991
I. Kalashnikova
Institute of Physiologically Active Compounds; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: dkfrvzh@gmail.com
俄罗斯联邦, Chernogolovka, Moscow Oblast’, 142432; Moscow, 119991
C. Devillers
Institute of Molecular Chemistry of the University of Burgundy
Email: dkfrvzh@gmail.com
法国, Dijon
M. Vorotyntsev
Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology; Faculty of Chemistry; Institute of Molecular Chemistry of the University of Burgundy
Email: dkfrvzh@gmail.com
俄罗斯联邦, Chernogolovka, Moscow Oblast’, 142432; Moscow, 125047; Leninskie Gory, Moscow, 119991; Dijon
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