Nanoparticle photochemistry via nano-impacts
- Authors: Bartlett T.R.1, Sokolov S.V.1, Compton R.G.1
-
Affiliations:
- Department of Chemistry, Physical and Theoretical Chemistry Laboratory
- Issue: Vol 52, No 12 (2016)
- Pages: 1131-1136
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188298
- DOI: https://doi.org/10.1134/S1023193516120041
- ID: 188298
Cite item
Abstract
We report the use of nano-impacts as a novel method for the study of photochemical reactions of individual nanoparticles (NPs). The conversion of gelatine stabilised silver bromide (AgBr) NPs to silver (Ag) NPs through photochemical reduction by ascorbic acid is studied mechanistically. Two mechanisms are proposed and investigated by monitoring the amount of electrochemically accessible AgBr against the time scale of conversion, measured through the use of the nano-impacts technique.
Keywords
About the authors
T. R. Bartlett
Department of Chemistry, Physical and Theoretical Chemistry Laboratory
Email: Richard.Compton@chem.ox.ac.uk
United Kingdom, South Parks Road, Oxford, OX1 3QZ
S. V. Sokolov
Department of Chemistry, Physical and Theoretical Chemistry Laboratory
Email: Richard.Compton@chem.ox.ac.uk
United Kingdom, South Parks Road, Oxford, OX1 3QZ
R. G. Compton
Department of Chemistry, Physical and Theoretical Chemistry Laboratory
Author for correspondence.
Email: Richard.Compton@chem.ox.ac.uk
United Kingdom, South Parks Road, Oxford, OX1 3QZ