Electrochemical doping of polyaniline with the tetracyanoquinodimethane anion
- Авторы: Abalyaeva V.V.1, Dremova N.N.1
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Учреждения:
- Institute of Problems of Chemical Physics
- Выпуск: Том 52, № 8 (2016)
- Страницы: 746-753
- Раздел: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188078
- DOI: https://doi.org/10.1134/S1023193516080024
- ID: 188078
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Аннотация
A new complex of aniline (An) with tetracyanoquinodimethane (TCQM) An(TCQM)4 has been obtained and studied. The redox cycling of polyaniline (PAni-sulfo) in a neutral electrolyte containing Cl– and ClO4− anions led to a replacement of the sulfate anion by the Cl– and ClO4− anions. The TCQM anion can also replace the sulfate anions in polyaniline (PAni) during the cycling of the latter in a neutral electrolyte containing TCQM anions. The introduction of TCQM in PAni creates conditions for generating nanocrystalline regions inside the polymer.
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Об авторах
V. Abalyaeva
Institute of Problems of Chemical Physics
Автор, ответственный за переписку.
Email: avva@icp.ac.ru
Россия, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
N. Dremova
Institute of Problems of Chemical Physics
Email: avva@icp.ac.ru
Россия, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
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