Email this article Electrochemical doping of polyaniline with the tetracyanoquinodimethane anion
- Authors: Abalyaeva V.V.1, Dremova N.N.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 52, No 8 (2016)
- Pages: 746-753
- Section: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188078
- DOI: https://doi.org/10.1134/S1023193516080024
- ID: 188078
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Abstract
A new complex of aniline (An) with tetracyanoquinodimethane (TCQM) An(TCQM)4 has been obtained and studied. The redox cycling of polyaniline (PAni-sulfo) in a neutral electrolyte containing Cl– and ClO4− anions led to a replacement of the sulfate anion by the Cl– and ClO4− anions. The TCQM anion can also replace the sulfate anions in polyaniline (PAni) during the cycling of the latter in a neutral electrolyte containing TCQM anions. The introduction of TCQM in PAni creates conditions for generating nanocrystalline regions inside the polymer.
About the authors
V. V. Abalyaeva
Institute of Problems of Chemical Physics
Author for correspondence.
Email: avva@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
N. N. Dremova
Institute of Problems of Chemical Physics
Email: avva@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
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