The method of double cathodic-anodic potential (current) pulses for synthesis of composite coatings Prussian blue–polypyrrole on optically transparent electrodes


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Resumo

An original method of one-step electrochemical deposition of electroactive composite films from a mixed solution of precursors of the organic and inorganic components in the mode of double cathodic–anodic pulses is used for the formation of Prussian blue/polypyrrole films on the surface of optically transparent electrodes. The deposition parameters are chosen (the order of deposition of components, the number and amplitude of polarizing pulses, the pulse length) which allow the deposition of composite films with good adhesion to the electrode surface and the high stability of the redox-transition Prussian blue/Prussian white.

Sobre autores

N. Talagaeva

Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology of Russia

Email: ks-chem@mail.ru
Rússia, pr. Akademika Semenova 1, Chernogolovka, Moskovskaya Oblast’, 142432; Miusskaya pl. 9, Moscow, 125047

P. Pisareva

Institute of Problems of Chemical Physics; Lomonosov Moscow State University

Email: ks-chem@mail.ru
Rússia, pr. Akademika Semenova 1, Chernogolovka, Moskovskaya Oblast’, 142432; Vorob’evy Gory 1, bld. 51, Moscow, 119234

A. Grebenko

Institute of Solid State Physics

Email: ks-chem@mail.ru
Rússia, ul. Akademika Osip’yana 2, Chernogolovka, Moskovskaya Oblast’, 142432

M. Vorotyntsev

Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology of Russia; Lomonosov Moscow State University

Email: ks-chem@mail.ru
Rússia, pr. Akademika Semenova 1, Chernogolovka, Moskovskaya Oblast’, 142432; Miusskaya pl. 9, Moscow, 125047; Vorob’evy Gory 1, bld. 51, Moscow, 119234

E. Zolotukhina

Institute of Problems of Chemical Physics; Mendeleev University of Chemical Technology of Russia

Autor responsável pela correspondência
Email: ks-chem@mail.ru
Rússia, pr. Akademika Semenova 1, Chernogolovka, Moskovskaya Oblast’, 142432; Miusskaya pl. 9, Moscow, 125047

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