Open Access Open Access  Restricted Access Access granted  Restricted Access Subscription Access

Vol 48, No 6 (2018)

Article

Processing Ash and Slag Wastes from Thermal Power Stations. Part 1

Podgorodetskii G.S., Gorbunov V.B., Agapov E.A., Erokhov T.V., Kozlova O.N.

Abstract

In accordance with the national energy strategy, the development of coal-fired power stations in Russia, especially in Siberia and the Far East, calls for utilization of their ash and slag wastes. The total quantity of ash and slag in Russian tailings exceeds 1.5 billion t. These wastes cover an area of more than 220 km2. The utilization of these wastes is no more than 10%. The most promising approaches are utilization of the wastes in construction materials or road building, or a hybrid approach in which valuable metals are extracted during the production of construction materials. Some fly ash can be used in agriculture. The physicochemical properties of ash and slag waste and correspondingly their applicability and the choice of technology will be determined by the mineral component of the coal and the methods by which the coal is burned. In order to use fly ash in construction, dry processing methods for ash and slag waste must be introduced. On the one hand, that involves greater capital expenditures on equipment and structures for storage, classification, crushing, and grinding of the ash and slag waste, as well as means of modifying their properties. On the other, increased transportation and organizational barriers must be expected. Examples of proposed processing technologies based on metal extraction and the production of construction materials are presented. To obtain iron-bearing concentrates, single-stage magnetic separation is mainly employed. However, the resulting quality of the concentrate is unsatisfactory. A better approach to the extraction of metals from ash and slag waste is flotation. At the same time, the available data indicate that the application of flotation may be limited by economic and organizational factors and associated environmental hazards. The conclusion is that the use of such technologies at thermal power stations that are already in operation is possible, with state support.

Steel in Translation. 2018;48(6):339-345
pages 339-345 views

Stability of the Transition Zones in a Steel–Vanadium Alloy–Steel Sandwich after Thermomechanical Treatment

Nechaikina T.A., Nikulin S.A., Rogachev S.O., Turilina V.Y., Baranova A.P.

Abstract

A priority in atomic power today is to develop a new material for fuel-rod casings in fast-neutron reactors. A radiation- and corrosion-resistant three-layer composite based on vanadium alloy and stainless steel has been developed. This composite potentially meets the operational requirements on fuel-rod casings in very challenging operating conditions (high temperatures, radiation, and aggressive media). The performance of this material depends on the quality of the joint between the three layers, which is determined by the preliminary deformation and heat treatment. In the present work, the influence of tempering on the chemical composition, structure, and strength of the joint between the vanadium alloy and steel in the sandwich obtained by hot pressing a three-layer pipe blank at 1100°C is studied. The components of the pipe are 20Kh13 (Russian standard) steel for the external layers and V–4Ti–4Cr vanadium alloy in the core. The structure and chemical composition at the interfaces is investigated by optical and electronic microscopy, with X-ray spectral analysis. The strength of the steel–alloy bond is assessed in compressive tests of an annular three-layer sample with a cut; acoustic-emission measurements are employed. Pressing is found to form a transition zone of thickness 10–15 μm between the vanadium alloy and the steel, which is characterized by diffusional interaction and has a variable chemical composition. This zone consists of a series of solid solutions, without the deposition of brittle phases, and consequently the junction between the layers is strong. No pores, peeling, or defect are observed at the steel–alloy junction. However, in compressive tests of semiannular three-layer samples with a cut after hot pressing, a crack is formed in the steel layer at the tip of the cut. Annealing at 800°C improves the transition zone by increasing the thickness corresponding to diffusional interaction. Consequently, in mechanical tests, the sandwich behaves as a monolithic material, without cracking or peeling between the steel and the vanadium alloy.

Steel in Translation. 2018;48(6):346-351
pages 346-351 views

Redistribution of Carbon Atoms in Differentially Quenched Rail on Prolonged Operation

Gromov V.E., Yur’ev A.A., Ivanov Y.F., Grishunin V.A., Konovalov S.V.

Abstract

The change in structure, phase composition, and defect substructure in the head of differentially quenched rail after the passage of gross traffic amounting to 691.8 million t is investigated over the central axis, at different distances from the top surface, by means of transmission electron microscopy. The results confirm that prolonged rail operation is accompanied by two simultaneous processes that modify the structure and phase composition of the plate-pearlite colonies: cutting of the cementite plates; and solution of the cementite plates. The first process involves cutting of the carbide particles and removal of their fragments, accompanied simply by change in their linear dimensions and morphology. The second process involves the extraction of carbon atoms from the crystal lattice of cementite by dislocations. That permits phase transformation of the metal in the rail, which is associated with marked relaxation of the mean binding energy of the carbon atoms at dislocations (0.6 eV) and at iron atoms in the cementite lattice (0.4 eV). The stages in the transformation of the cementite plates are as follows: the plates are wrapped in slipping dislocations, with subsequent splitting into slightly disoriented fragments; the slipping dislocations from the ferrite lattice penetrate into the cementite lattice; and the cementite dissolves with the formation of nanoparticles. The cementite nanoparticles are present in the ferrite matrix as a result of their transfer in the course of dislocational slip. On the basis of equations from materials physics and X-ray structural data, the content of carbon atoms at structural elements of the rail steel is assessed. It is found that prolonged rail operation is accompanied by significant redistribution of the carbon atoms in the surface layer. In the initial state, most of the carbon atoms are concentrated in cementite particles. After prolonged rail operation, the carbon atoms and cementite particles are located at defects in the steel’s crystalline structure (dislocations, grain and subgrain boundaries). In the surface layer of the steel, carbon atoms are also observed in the crystal lattice based on α iron.

Steel in Translation. 2018;48(6):352-356
pages 352-356 views

Thermodynamics of the Interactions in Fe–Mg–Al–La–O Melts

Mikhailov G.G., Makrovets L.A., Smirnov L.A.

Abstract

Today, rare-earth elements are mainly introduced in alloys in the form of misch metal, which is a natural mixture of rare-earth elements (with atomic numbers 57–71). This mixture contains about 50 wt % cerium. The primary components of the mixture are generally cerium, lanthanum, and niobium. The specific composition depends on the particular field from which they were drawn. The variable composition of this mixture may significantly impair its effectiveness in alloying. The ratio of the individual elements in the mixture cannot be determined experimentally for each grade of steel, because of the prohibitive expense of such separation. However, thermodynamic modeling permits determination of the optimal concentration of each rare-earth element and the composition of the misch metal. In the present work, thermodynamic modeling is applied to the interaction of magnesium, aluminum, and lanthanum with oxygen in liquid iron. The thermodynamic model of the reduction of steel by mixtures of such active metals is considered. On the basis of literature data regarding the phase diagrams of the MgO–Al2O3, MgO–La2O3, and La2O3–Al2O3 systems, the coordinates of points of invariant equilibrium in the MgO–La2O3–Al2O3 system are established. The MgO–La2O3–Al2O3 phase diagram is plotted. That permits the identification of all possible equilibria in the reduction of steel by magnesium, aluminum, and lanthanum and also the determination of corresponding descriptive equations. The activity of the components in liquid oxide melts is determined by the theory of subregular ionic solutions, taking account of the influence of the oxide melt’s composition on the coordination number of the cations. The activity of the components in metallic melts that are conjugate with the oxide systems is determined by means of the Wagner theory on the basis of first-order reaction parameters. The equilibrium constants of the reduction of steel by the given elements are established by indirect thermodynamic calculations. On the basis of the results, the solubility surface of the components in Fe–Mg–Al–La–O melts is constructed. That permits the identification of regions where the composition of the liquid metal corresponds to a particular oxide phase.

Steel in Translation. 2018;48(6):357-361
pages 357-361 views

Optimizing the Pilot Testing of ERP Systems

Zimin V.V., Burkova I.V., Mit’kov V.V., Zimin A.V.

Abstract

In the creation of ERP systems, it is important to plan the pilot testing. In pilot projects (also known as experimental projects), the main functions of the system are tested by a limited set of advanced users. In planning the pilot testing, the key is to determine its extent. With too little testing, fundamental functions of the system may not be checked, and the probability of detecting significant errors only at complete rollout will be high. With excessive testing, the work required in the pilot project will be considerably increased, and the required speed and flexibility will not be attained in testing the basic functions. The effectiveness of pilot testing will be no better than the effectiveness of full-scale introduction. A mathematical formulation of the determination of the optimal extent of pilot testing is developed on the basis of the generation of a portfolio of IT services and their scheduling in the creation of the ERP system for a large steel company. The solution of this problem takes the form of a set of services that must be verified and the relations between them, within the specified constraint on the resources devoted to testing, such that optimal results are obtained. The solution is obtained by network programming, based on a structurally similar network representation of the relevant criteria and constraints. A solution procedure is outlined, along with an example of its use. In this procedure, dichotomous programming is used to solve individual problems. The approximate solutions obtained may be improved by solving a double network-programming problem. The branch and bound method may be used to find the global optimum of the initial problem. In that approach, the boundaries are values of the target functions for the approximate solutions. Generalization of this problem is based on the preferences of IT-service users regarding the quality of verification of different relations between the services. Those preferences may be taken into account by weighting the corresponding relationships. That leaves the basic solution procedure unchanged.

Steel in Translation. 2018;48(6):362-367
pages 362-367 views

Thermodynamics of Oxygen Solutions in Ni–Cr Melts Containing Aluminum

Dashevskii V.Y., Aleksandrov A.A.

Abstract

The influence of aluminum on the solubility of oxygen in Ni–Cr melts is considered on the basis of thermodynamic analysis. Very low aluminum concentrations have practically no influence on the oxygen concentration in the melt, which is determined by the chromium content. When the aluminum content exceeds 0.01%, it determines the solubility of oxygen in the melt, in all cases. The minimum oxygen concentration corresponds to about 0.2% Al. With increase in chromium content in the melt, the minimum oxygen concentration increases. It is 2 × 10–3%, 7 × 10–3%, and 10–2% for nickel alloys with 10%, 20%, and 30% Cr, respectively.

Steel in Translation. 2018;48(6):368-371
pages 368-371 views

Coordination of the Batch Distribution at the Blast-Furnace Mouth and the Gas-Flux Distribution in the Hearth

Tarakanov A.K., Lyalyuk V.P., Kassim D.A., Otorvin P.I., Pinchuk D.V.

Abstract

Coordinated parameter selection of the batch charged at the top of the blast furnace and the blast injected in the hearth is evaluated as a means of improving furnace performance.

Steel in Translation. 2018;48(6):372-375
pages 372-375 views

Energy–Technology Efficiency of Ferroalloy Electrofurnaces

Shkirmontov A.P.

Abstract

Improvement in the energy efficiency of electrofurnaces for large-scale ferroalloy production with carbon reducing agents is considered, on the basis of the operational index Sh. It is found that increase in Sh corresponds to decrease in power consumption.

Steel in Translation. 2018;48(6):376-380
pages 376-380 views

Effects of Decreasing the Initial Rolling Temperature in Three-High Roughing Stands

Smirnov E.N., Smirnov A.N., Sklyar V.A., Belevitin V.A., Eron’ko S.P., Pivovarov R.E.

Abstract

Research on expanding the product range and minimizing the energy costs at a linear medium-bar mill with three-high roughing stands is discussed. The possibility of controlling the mechanical properties of the product by decreasing the initial rolling temperature is considered. Despite the improvement in mechanical properties, decrease in the initial rolling temperature in the range 900–950°C is accompanied by increase in current load at the primary drive and decrease in dimensional precision of the product.

Steel in Translation. 2018;48(6):381-387
pages 381-387 views

Controlled Cooling of Strip Coils on the Conveyer of a Hot-Rolling Mill

Chashchin V.V.

Abstract

Research shows that the controlled cooling of strip coils should not begin in storage but rather during coil transportation to the store or to the next technological operation. That increases the effectiveness of coil cooling, thanks to the greater heat content of the metal or the greater cooling rates. On the basis of the research, proposals are made for controlled cooling of strip coils in existing lines for the transportation of hot coils to stores, with slow-cooling (thermostat) sections and accelerated-cooling sections. Controlled cooling of strip coils is also possible in newly constructed and reconstructed lines that transport coils of hot-rolled strip to the next technological operation, without intermediate storage.

Steel in Translation. 2018;48(6):388-392
pages 388-392 views

Optimal Mechanical Properties of Structural Steel for the Prevention of Embrittlement

Shiyan A.V., Meshkov Y.Y., Zimina G.P.

Abstract

With a view to ensuring structural stability of steels and alloys, a system for harmonizing the plasticity, strength, and deformation resistance of structural steels is developed. Principles for the formation of such properties are outlined. Means of controlling the change in these properties are considered. The sensitivity of some characteristics of the metal to changes in others is discussed. The reserves of strength in various structural steels are compared in terms of their ability to resist brittle failure, on the basis of the mechanical stability Kms and the embrittlement expressed as the deformational strength (fracture resistance) Br. The quality of structural steels is assessed in terms of their ability to resist embrittlement. The proposed approach here is to assess the quality of structural steels in terms of their deformational strength at specified yield point σ0.2, which reflects the resistance to embrittlement.

Steel in Translation. 2018;48(6):393-402
pages 393-402 views

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies