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Vol 48, No 2 (2018)

Article

Influence of a Rotary Electromagnetic Field and Mechanical Stimulation on the Production of Cobalt Nanopowder by Reduction with Hydrogen

Nguyen V.M., Konyukhov Y.V., Ryzhonkov D.I.

Abstract

Cobalt nanopowder is very promising for use in science, engineering, industry, and medicine. The present study focuses on the kinetics of nanopowder production by the reduction of cobalt oxide with hydrogen in an electromagnetic field, under the action of a bed of ferromagnetic particles rotating in the electromagnetic field. Cobalt oxide (Co3O4) nanopowder is obtained by the thermal decomposition of cobalt hydroxide Co(OH)2 deposited from 10% ionic solutions of cobalt nitrate Co(NO3)2 and sodium hydroxide NaOH at 20°C, with pH 9. Cobalt nanoparticles are produced from Co3O4 nanopowder in a modified UAP-3 vortical bed system with a built-in furnace and flow-through reactor. The amplitude of the magnetic induction within the reactor is 0.16 T. The experimental reduction temperature is selected on the basis of thermogravimetric analysis of the initial Co(OH)2 sample. The kinetic parameters of hydrogen reduction with linear heating and in isothermal conditions are calculated on the basis of the Freeman–Carroll and McKewan models, respectively. The rate of cobalt- nanopowder production slows in an electromagnetic field (by up to 14% at 250°C), on account of hindrance to the adsorption of hydrogen atoms at the surface of the metallic nanoparticles formed. However, mechanical stimulation in a vortical bed increases the rate of the process by a factor of 4–5 as a result of activation. The properties of the initial material and the products are studied by thermogravimetric analysis, X-ray diffraction analysis, scanning electron microscopy, and measurement of the specific surface by low-temperature nitrogen absorption. In the reduction of the samples, smaller cobalt nanoparticles are produced in the presence of an electromagnetic field. Mechanical stimulation in a vortical bed results in aggregation of the cobalt nanoparticles and the formation of microgranules.

Steel in Translation. 2018;48(2):73-77
pages 73-77 views

Temperature Differences in the Mold of a Continuous-Casting Machine with a New Cooling System

Stulov V.V.

Abstract

Attention focuses on the processes in the mold of a continuous-casting machine when using a patented new cooling system. In particular, the temperature differences in the steel billet and in the wall over the mold height are of interest in modeling the casting processes, because those differences affect the quality of the billet produced. A literature review covers research on the slag-forming mixture, which affects the heat flux from the billet to the mold. Non-Russian authors highlight mild cooling of the mold in selecting the slagforming mixture. Improvement of billet cooling in the mold permits improvement in the surface quality of the slab, extension of mold life, and increase in productivity. According to numerous authors, that may be accomplished by mathematical modeling of the process. The mold cooling depends directly on the convective motion of liquid steel in the mold, a topic addressed by many non-Russian authors. Researchers have considered systems in which the heat pipes in the cooling system of the mold are based on porous material, with water and air as the working fluid, and those in which liquid droplets on nanostructured superhydrophilic surfaces are evaporated. Mold cooling at steel casting rates higher than 7 m/min, accompanied by increase in the heat-flux density, is of great importance, as reflected by the number of studies published. The relations between the basic process parameters are determined by means of Rayleigh dimensionality theory. The basic parameter selected is the temperature difference in the metal mold wall, which depends on the casting rate (the time that the billet is in the mold), the properties of the steel (specific heat, thermal diffusivity), the thermal conductivity of the mold wall, and the temperature difference in the cast steel. In determining the exponents in the dimensionless relations, the available experimental data regarding the dependence of the heatflux density on the casting rate and the parameter of the steel are taken into account. On the basis of the ratio Δtme/tme obtained (where Δtme is the mean temperature difference over the wall thickness and tme is the mean wall temperature) for molds with the existing and new (patented) cooling systems, the temperature difference in the steel billet may be determined. For the two cooling systems compared, Δtme1 = 450°C and Δtme2 = 231°C. Consequently, Δtme1tme2 = 1.95. The smaller temperature difference Δtme2 indicates milder cooling of the mold with the new cooling system.

Steel in Translation. 2018;48(2):78-81
pages 78-81 views

Quality of the Seam in Welding under Flux by Means of Barium–Strontium Carbonatite

Kozyrev N.A., Kryukov R.E., Usol’tsev A.A., Prokhorenko O.D., Aimatov V.G.

Abstract

The use of barium–strontium carbonatite in the modification and refining of ferrocarbon alloys is considered. Its use in welding fluxes is proposed. That possibility is analyzed for the example of BSK-2 barium–strontium modifier (Technical Specifications TU 1717-001-75073896–2005) produced by OOO NPK Metalltekhnoprom, with the following composition: 13.0–19.0% BaO, 3.5–7.5% SrO, 17.5–25.5% CaO, 19.8–29.8% SiO2, 0.7–1.1% MgO, 2.5–3.5% K2O, 1.0–2.0% Na2O, 1.5–6.5% Fe2O3, 0–0.4% MnO, 1.9–3.9% Al2O3, 0.7–1.1% TiO2, and 16.0–20.0% CO2. A production technology is proposed for a flux additive containing 70% barium–strontium carbonatite and 30% liquid glass. Several welding-flux compositions based on slag from silicomanganese production are tested. The flux additive is introduced in quantities of 1, 3, and 5%. The specifics of welding under the proposed welding fluxes are determined. The chemical composition of the fluxes, the slag crusts, and the metal in the weld seam are determined by X-ray spectral analysis. The weld seams are studied metallographically. It is possible in principle to use barium–strontium carbonatite as a refining additive to welding fluxes; it also provides a protective atmosphere for the welded metal. By introducing barium–strontium carbonatite, the content of nonmetallic inclusions (nondeforming silicates, point oxides, and brittle silicates) in the weld seam may be reduced, and the desulfurizing properties of the welding fluxes may be enhanced. The introduction of up to 5% barium–strontium carbonatite in welding fluxes based on silicomanganese slag ensures that the metal in the weld seam has ferrite–pearlite structure of Widmanstatten type. The grain size is slightly reduced here: from a score of 4 to 4–5.

Steel in Translation. 2018;48(2):82-86
pages 82-86 views

Luders Deformation in Weld Joints

Danilov V.I., Smirnov A.N., Gorbatenko V.V., Orlova D.V., Danilova L.V.

Abstract

The elastoplastic transition in welded low-carbon steel samples is considered. Two methods of manual arc welding of floating-electrode type are employed: a traditional steady arc; and pulsed welding with controlled heat consumption. In terms of the structural characteristics and mechanical properties of the welded metal, the methods are identical. In both cases, extended elastoplastic transition by the nucleation and propagation of Luders bands is observed. However, the underlying process is different. In the traditional steady arc, the Luders bands are formed in the applied metal initially as diffuse regions where the deformation is localized. These regions fill the seam and convert it to the plastically deformed state. The moving fronts of the bands are finally shaped in the thermal-influence zones and pass to the basic metal. The velocity and morphology of the fronts match those of fronts in uniform objects of the same steel. When using a pulsed arc, Luders bands appear some distance from the weld seam, at the clamps of the loading device. Up to the thermal- influence zones, the velocity and morphology of the fronts correspond to those for the basic metal. At the fusion boundary, the front stops and forms the nucleus of a new band, which expands in the seam metal. This new band first transforms the applied metal to the deformed state and then creates a moving front in the opposite thermal-influence zone. The velocity of the front differs by an order of magnitude in the applied metal and the basic metal. The weld seam determines the nucleation of Luders bands. An explanation is offered for the different origins of the elastoplastic transition in the two welding methods. In traditional welding with a steady arc, the local long-range stress is considerably higher in the thermal-influence zones than in the basic metal. Therefore, the nucleation of Luders bands is a relaxational process in this case. In pulsed arc welding, the local long-range stress is higher in the basic metal, where the Luders bands appear. The results may be used in selecting the test conditions for power-system equipment.

Steel in Translation. 2018;48(2):87-92
pages 87-92 views

Disintegration of Composite Electroexplosive Coatings in Spark Erosion

Romanov D.A., Protopopov E.V.

Abstract

A mathematical model is proposed for the destruction of electroexplosive W–Cu, Mo–Cu, W‒C–Cu, Mo–C–Cu, Ti–B–Cu, and TiB2–Cu composite coatings under spark erosion associated with the opening of electrical contacts. The model describes the evaporation of the electrodes under the action of the heat flux due to sparking when the electrical contacts open. In this model, the resistance of the electrical contacts during the tests is assumed to be 40–50 μΩ. The model corresponds to the heating of a half-space by a normal pulsed surface heat source uniformly distributed over an area of specified radius, with a specified heating time. The energy distribution of the pulse over time is approximated by a rectangular pulse. The finite pulse length is taken into account in solving the heat-conduction equation in cylindrical coordinates for a plane instantaneous heat source. The vapor pressure of the metal is determined from the surface temperature. The calculations assume a contact voltage of 380 V; a current of 3 A; a spark discharge of length 150 μs; and a discharge–surface contact spot of radius 152 μm. The following parameters are determined: the surface temperature of pure electrodes; the surface temperature of the composite coatings; the depth of the evaporation layer for pure electrodes; the mass loss of the composite coating after a single discharge pulse; the relative change in bulk resistance of the pure electrodes and composite coatings to electroerosion; and the relative change in mass resistance of the pure electrodes and composite coatings to electroerosion. The content of the elements in the composite coating is determined. The model results are in good agreement with experimental data, especially for the ternary systems W–C–Cu, Mo–C–Cu, and Ti–B–Cu. The results are also in adequate agreement with literature data. For the binary systems W–Cu and Mo–Cu, the discrepancies may be attributed to the approximations made in the model.

Steel in Translation. 2018;48(2):93-96
pages 93-96 views

Transformation of Carbides in Prolonged Rail Operation

Ivanov Y.F., Yur’ev A.A., Gromov V.E., Konovalov S.V., Peregudov O.A.

Abstract

The evolution of the carbide phase in the surface layers of bulk-quenched rails (after the passage of 500 and 1000 million t of traffic) and differentially quenched rails (after the passage of 691.8 million t) to a depth of 10 mm at the central axis of the rail cross section and at the nearby rounded section is studied by transmission electron-diffraction microscopy. The grains of plate pearlite, ferrite–carbide mixture, and structure-free ferrite are analyzed. The carbide phase in the surface layers of the steel changes in two mutually complementary processes during rail operation: (1) cleavage of cementite particles with subsequent entrainment in ferrite grains or plates (in the pearlite structure); (2) cleavage and dissolution of cementite particles, with transfer of carbon atoms to dislocations (in Cottrell atmospheres and in dislocational cores), which transport them to the ferrite grains (or plates), where cementite nanoparticles are formed again. In the previous location of the plates, fragmented dislocational substructure appears. The boundaries of the fragments are found at the positions previously occupied by cementite α-phase boundaries. The solution of cementite is mainly due to the energy of carbon atoms at dislocation cores and subboundaries in comparison with the cementite lattice. The binding energy of the carbon atom and the dislocations is 0.6 eV and the binding energy of the carbon atom and the subboundary is 0.8 eV, as against 0.4 eV for the carbon atom in cementite. Elastoplastic stress fields are formed; their stress concentrators are intra- and interphase boundaries of ferrite and pearlite grains, cementite plates and ferrite of the pearlite colonies, and globular cementite and ferrite particles. Those are also the basic sources of curvature and torsion in the crystal lattice of the rail steel. On approaching the contact surface, the number of stress concentrators increases, and the internal long-range stress fields are of greater amplitude.

Steel in Translation. 2018;48(2):97-103
pages 97-103 views

Using Small Particles with High Moisture Content in Iron Production by Liquid-Phase Reduction

Gudim Y.A., Tokovoi O.K.

Abstract

Drying of small wet particles by mixing with lime powder to permit safe handling in continuous systems for iron production by liquid-phase reduction is investigated. The quantity of lime powder most suitable for the drying of concentrate with different initial moisture contents is determined. A system is proposed for the use of wet batch in continuous industrial systems for iron production.

Steel in Translation. 2018;48(2):104-108
pages 104-108 views

Model for Predicting the Lankford Coefficient of Industrial Sheet of Automotive Steels

Vasilyev A.A., Sokolov D.F., Sokolov S.F., Glukhov P.A., Kolbasnikov N.G., Mitrofanov A.V.

Abstract

A model is proposed for predicting the Lankford coefficient of steel sheet produced for the auto industry at PAO Severstal. The set of empirical model parameters is determined using an experimental database on the mean Lankford coefficient (for 138 strips of 13 steels differing greatly in composition) and additional databases on calculated steel microstructure parameters after hot rolling, and after heat treatment of cold-rolled strips. The mean error in calculations of the Lankford coefficient using the model is 7.1%. It is found that the Lankford coefficient is determined not only by the carbon content in the solid solution before cold rolling but also by the amount of carbon deposited at the ferrite grain boundaries in the form of tertiary cementite. The additional free carbon appearing in the solution when the tertiary cementite particles dissolve on heating of the cold-rolled sheet significantly affects the recrystallization and the texture formation.

Steel in Translation. 2018;48(2):109-115
pages 109-115 views

Influence of the Structure of Fe–Si–Mg–Rare Earth Modifiers on the Production of Compacted Graphite Iron for Camshafts

Boldyrev D.A., Ivanov S.V., Popova L.I., Davydov S.V.

Abstract

The structure of a modifier in two forms (ingot and chip) for the production of compacted graphite iron (also known as vermicular graphite iron) is investigated by means of an electron microscope and also by X-ray microspectral analysis. The possibility of qualitative identification of the phase composition and surface macroanalysis of the modifier particles is considered.

Steel in Translation. 2018;48(2):116-119
pages 116-119 views

Influence of the Final Rolling Temperatures on the Relation between the Composition and the Mechanical Properties of K60 Pipe Steel

Gorbatenko V.P., Petrushchak S.V.

Abstract

The influence of alloying and microalloying elements on the mechanical properties of pipe-steel sheet (strength category K60) depends on the temperature in low-temperature controlled rolling, on account of the polymorphous γ → α and eutectoid transformation of austenite in the mill’s finishing stand.

Steel in Translation. 2018;48(2):120-125
pages 120-125 views

Influence of Sulfur on the Anisotropy of the Plastic Properties in Structural Steel

Rudenko S.P., Val’ko A.L., Parfenchik V.N.

Abstract

The influence of the preparation of structural steels on the anisotropy of the plastic properties is investigated. With increase in sulfur content, the banding and anisotropy of mechanical properties such as the impact strength is considerably increased. For example, in high-quality steel with the limiting sulfur content, the impact strength differs by a factor of 6–8 in the longitudinal and transverse directions.

Steel in Translation. 2018;48(2):126-129
pages 126-129 views

Influence of Intermittent Quenching and Self-Tempering on the Mechanical Properties of Rebar Steel

Kanaev A.T., Bogomolov A.V., Kanaev A.A., Reshotkina E.N.

Abstract

The influence of deformation and heat treatment on the mechanical properties of rebar steel is investigated on a pilot system. Specifically, with intermittent quenching and subsequent self-tempering, the intense-cooling time determines the tempering temperature of the quenched steel and hence the final mechanical properties of the rebar. The influence of the water pressure in the intense-cooling chamber on the uniformity of the mechanical properties is studied for steel with 0.31, 0.32, and 0.35% C; the water pressure is varied from 0.2 to 0.6 MPa. On that basis, it is established that the water pressure in the cooling chamber must be no less than 0.3 MPa, and the carbon content in the steel must be more than 0.32% in order to ensure that the mechanical properties of the rebar steel conform to the AT500 strength class according to State Standard GOST 10884–2004.

Steel in Translation. 2018;48(2):130-134
pages 130-134 views

Heavy-Metal Extraction from Wastewater by Means of Iron Nanopowder

Konyukhov Y.V.

Abstract

Two methods of producing iron nanopowder that is resistant to atmospheric oxidation are considered. The properties of the nanopowder are investigated by thermogravimetric analysis, X-ray diffraction analysis, and scanning electron microscopy. Its specific surface is measured by low-temperature nitrogen absorption. The effectiveness of the iron nanopowder in the removal of heavy metals (lead, copper, and zinc) from industrial wastewater is assessed for model solutions and for wastewater from the gas-processing system in the blast-furnace shop at PAO Severstal. The concentrations of dissolved ions are determined by ion-selective potentiometry and atomic-emission spectrometry. For purposes of comparison, experiments are conducted with natural sorbents (shungite, glauconite) and artificially activated K coal.

Steel in Translation. 2018;48(2):135-141
pages 135-141 views

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