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Том 46, № 8 (2016)

Article

Thermal solution of coal to obtain binder for refractories. 1. Binder production

Bazegskii A., Shkoller M.

Аннотация

Experimental coal-based pitch obtained by the controlled action of solvent (a hydrogen donor) on the thermally activated organic mass of coking coal is studied. The basic parameters required for the production of such pitch are determined: the temperature; the duration of the process; and the proportions of the components. The pitch produced matches high-temperature coke-plant pitch in terms of the yield of volatiles, the softening temperature, the content of toluene- and quinoline-insoluble materials, and structure. The maximum conversion and best quality of the pitch (in terms of the traditional characteristics) are obtained when using coal with the maximum vitrinite content and plastic-layer thickness. Pitch produced by the solution of coal is suitable for use as a binder in the production of refractories and its content of carcinogenic benzo(a)pyrene is an order of magnitude less than that of standard coal pitch, since it is obtained directly from coal, without the need for the high temperatures used in coking.

Steel in Translation. 2016;46(8):533-537
pages 533-537 views

Thermal stress in iron-ore pellets with differentiated porosity

Pavlovets V., Gerasimuk A.

Аннотация

The thermal stresses in three types of iron-ore pellets with differentiated porosity are compared. The thermal stress of pellets obtained by the spraying of wet batch onto the batch coating and onto pelletized materials is analyzed. The influence of the porosity and thermal mass of the pellets on the thermal-stress distribution over the pellet cross section is determined. The variation in the strength of pellets with differentiated porosity over the cross section is assessed in the presence of a dynamic temperature field over the porous sphere. The role of the thermal mass in the core and shell of the pellet is also evaluated. The action of thermal stress in activating the sintering of iron-ore pellets is analyzed. Recommendations for improving the thermal conditions in pellet roasting are outlined. The best pore structure is obtained by forced nucleation of pellets, which results in elevated porosity in the core.

Steel in Translation. 2016;46(8):538-543
pages 538-543 views

Thermomechanical properties of molds based on different binders and casting quality

Chernyshov E., Evlampiev A., Korolev A., Ivanova L., Moiseeva O.

Аннотация

The thermomechanical properties of foundry sand are analyzed. The thermal and dynamic action of the melt on the mold wall during the casting and solidification of metal is considered, along with its role in the formation of surface defects. The influence of the heating time on the deformation of common types of foundry sand is determined by simulating industrial ingot casting. The deformability of the foundry sand is related to the defects that form on the ingots and the pliability of the sand. Measures are proposed to prevent surface defects. Scabs, gaps, and hot buildup on castings may be attributed to deformational changes and disintegration in the surface layers of the foundry sand. In terms of surface-defect prevention and environmental protection, sodium-silicate foundry sand and phosphate sands are the best.

Steel in Translation. 2016;46(8):544-547
pages 544-547 views

Influence of hybrid plastic deformation on the microstructure and mechanical properties of carbon-steel wire

Chukin M., Polyakova M., Gulin A.

Аннотация

Since the mechanical properties of metals and alloys with ultrafine-grain structure are of great practical interest, the development of continuous methods of intense plastic deformation deserves attention. The introduction of nanostructuring methods in existing production processes is subject to numerous constraints, mainly associated with the dimensions of the machined workpiece. Continuous methods of intense plastic deformation must be introduced, with corresponding gains of expediency and productivity. The combination of different types of plastic deformation is promising. Carbon-steel wire is studied in the present work. If drawing is combined with external loading, its applicability in wire production may be greatly expanded. If drawing is combined with flexure and torsion, a new production technology may be developed for the production of ultrafine-grain components. In this approach, continuously moving wire is subjected to tensile deformation (by drawing), flexural deformation (on passing through a system of rollers), and torsional deformation. The instruments employed are versatile and compatible with existing industrial equipment. If drawing is combined with flexure and torsion, the carbon-steel wire produced are characterized by ultrafinegrain structure. This approach permits modification of the mechanical properties of the wire over a broad range, without loss of strength or plasticity.

Steel in Translation. 2016;46(8):548-551
pages 548-551 views

Changes in ultrasound velocity in the plastic deformation of high-chromium steel

Barannikova S., Bochkareva A., Lunev A., Shlyakhova G., Zuev L.

Аннотация

The change in ultrasound velocity in the plastic deformation of high-chromium 40X13 stainless steel with ferrite–carbide structure (initially), martensite structure (after quenching), and sorbite structure (after high tempering) is investigated. The loading curve is different for each state. In the initial state, the loading curve is practically parabolic. In the martensitic state, linear strain hardening is the only stage. In the sorbitic state, a three-stage curve is observed. The structure of the steel after different types of heat treatment is studied by optical and scanning probe microscopy. In parallel with the recording of the loading curve, the change in properties of the ultrasonic surface waves (the Rayleigh waves) in the steel under tension is measured. To determine the speed of the Rayleigh waves, rectangular pulses (length 100 ns) are generated periodically at the input of the emitting piezoconverter and the wave is recorded after passage through the sample by the receiving piezoconverter, which is connected to a digital oscillograph. The resulting digital signal is used to measure the time from pulse generation to the appearance of a signal at the receiver output. The distance between the converters is constant. The changes in the ultrasound velocity during active loading are determined by the plastic flow—that is, by the stages in the corresponding loading diagram. The structure of the steel determines not only the type of deformation curve in uniaxial extension but also the dependence of the ultrasound velocity on the strain.

Steel in Translation. 2016;46(8):552-557
pages 552-557 views

Influence of the chromium concentration on structure formation in liquid chromonickel alloys

Tyagunov A., V’yukhin V., Tyagunov G., Baryshev E., Akshentsev Y.

Аннотация

The electrical resistivity of liquid nickel–chromium alloys is studied as a function of the temperature and concentration. Experimental data indicate that the dependence of the alloys’ electrical-resistance isotherms on the concentration is nonlinear. On the basis of the temperature and concentration dependence of the electrical resistivity of nickel and chromium alloys, the optimal conditions for the formation of microhomogeneous and equilibrium structure in the melt may be determined. The electrical-resistance isotherms of chromonickel alloys may be qualitatively explained on the basis of percolation theory and a quasi-chemical model of the microheterogeneous structure of molten metal alloys. The structure formation of chromonickel melts with increase in chromium concentration is characterized by the successive formation of clusters with different structure and dimensions.

Steel in Translation. 2016;46(8):558-562
pages 558-562 views

Solution of niobium in iron during arc surfacing

Sarychev V., Khaimzon B., Nevskii S.

Аннотация

The solution of niobium in iron during arc surfacing is simulated. The model is based on diffusional dissolution of niobium particles in metals. It includes diffusion equations, initial and boundary conditions, and also the equations of motion of the boundary between the media. The diffusion coefficient in liquid iron is assumed to much exceed that in the solid solution. The solution of the Stefan diffusional problem within the solid is found as a Fourier series in terms of cosines; the solution within the liquid is found in terms of error functions. The time for the dissolution of niobium is determined. It is 10–100 s for 10-μm particles at high temperatures.

Steel in Translation. 2016;46(8):563-566
pages 563-566 views

Degradation of rail-steel structure and properties of the surface layer

Ivanov Y., Morozov K., Peregudov O., Gromov V.

Аннотация

The change in the structure–phase states and defect substructure of the rail surface after prolonged operation (passed tonnage of 500 and 1000 million t) is studied by optical microscopy, by scanning and transmission electron diffraction microscopy, and by measurement of the microhardness and tribological characteristics. It is found that the wear rate increases by a factor of 3.0 and 3.4 after passed tonnage of 500 and 1000 million t, respectively, while the frictional coefficient is reduced by a factor of 1.4 and 1.1, respectively. After 500 million t, the cementite plates break down completely, and rounded cementite particles (10–50 nm) are formed. After 1000 million t, the initial stage of dynamic recrystallization is noted. Possible explanations of the observations are discussed. Two competing processes may occur in rail operation: (1) fragmentation of the cementite particles, with their subsequent entrainment in the ferrite grains or plates (in the pearlite structure); (2) fragmentation and subsequent solution of the cementite particles, with transfer of the carbon particles to dislocations (Cottrell atmospheres) and transportation of carbon atoms by dislocations within the ferrite grains (or plates), culminating in the formation of cementite nanoparticles.

Steel in Translation. 2016;46(8):567-570
pages 567-570 views

Forging and pressing technology at PAO Ruspolimet

Marchuk V., Chuchkov A., Martynov S.

Аннотация

New developments in forging and pressing technology at PAO Ruspolimet are considered. New methods of producing shells, disks, plates, and shafts are presented.

Steel in Translation. 2016;46(8):571-575
pages 571-575 views

Influence of the composition of high-temperature nickel-alloy electrodes on the ingot composition in vacuum arc remelting

Korzun E., Klochai V., Ryabtsev A.

Аннотация

Statistical analysis of the chemical composition of high-temperature VZh159 nickel alloy in vacuum-induction melting and vacuum arc remelting yields regression equations that may be used to predict the metal composition in the ingots obtained by vacuum arc remelting as a function of the components in the consumable electrodes. The variation in oxygen, carbon, nitrogen, sulfur, and phosphorus concentrations in remelting is determined. The results are used in the design of production processes for high-temperature nickel-alloy ingots at PAO Ruspolimet.

Steel in Translation. 2016;46(8):576-582
pages 576-582 views

Indirect reduction in blast-furnace smelting

Kurunov I., Filatov S., Tikhonov D., Basov V.

Аннотация

The influence of the intensity of blast-furnace smelting on the effectiveness of the indirect reduction of iron from wustite is considered on the basis of the Rist model, for specially prepared batch and coke of satisfactory quality. In the case of practically stable and effective reduction, broad variation in the smelting intensity in terms of oxygen is associated with acceleration of the indirect reduction, on account of increase in the concentration of reducing agents in the gas, increase in their consumption, and increase in the gas–batch contact surface. These results do not confirm the finding from the 1950s and 1960s that the dependence of the productivity and coke consumption on the smelting intensity is extremal.

Steel in Translation. 2016;46(8):583-588
pages 583-588 views

Influence of mold flux on the thermal processes in the mold

Anisimov K., Longinov A., Gusev M., Zarubin S.

Аннотация

Analysis of the literature on the thermophysical properties of mold flux shows that the measurement results for the thermophysical properties of the slag vary significantly, depending on the method employed. On that basis, a model is proposed for calculating the heat flux in the system consisting of the ingot, the slag film, and the mold. Literature data regarding the properties of the slag and industrial data regarding the mold’s wall temperature are employed here. The proposed model permits investigation of the heat flux as a function of the thickness and physicochemical properties of the mold flux.

Steel in Translation. 2016;46(8):589-594
pages 589-594 views

Formation and prevention of flexure defects at the surface of cold-rolled steel strip

Mazur V., Pargamonov E.

Аннотация

The formation of flexure defects when coils of thin cold-rolled steel strip are unwound is considered. The influence of the strip thickness, surface roughness, temperature, properties of the steel, and other factors on the formation of such defects is analyzed. Measures are proposed for the prevention of the defects.

Steel in Translation. 2016;46(8):595-601
pages 595-601 views

Influence of recrystallizing annealing on the properties of high-alloy isotropic steel with ultralow magnetic losses

Cheglov A., Pogodaev A., Yusupov V., Bakhtin S., Barybin D., Bakhtin A.

Аннотация

A technology is developed for the production of highly alloyed (with up to 3% Si) isotropic electrical steel characterized by ultralow magnetic losses (P1.5/50 ≤ 2.70 W/kg for strip of rated thickness 0.50 mm). The structure, texture, and magnetic and mechanical properties of vacuum-treated (<0.005% C) cold-rolled strip consisting of high-silicon steel (alloyed with >1% Al and >0.015% Sb) is investigated as a function of the heating rate and also the temperature and holding time in recrystallizing annealing. By refining the boundary conditions in the recrystallizing annealing of cold-rolled isotropic electrical steel, optimal grain size is obtained, and the pole densities of cubic orientations in the texture are increased. That reduces the magnetic losses.

Steel in Translation. 2016;46(8):602-605
pages 602-605 views

Magnetic properties and fine structure of amorphous Fe–Ni–Si–B alloys

Vavilova V., Korneev V., Kornienkov B., Libman M., Molotilov B., Kadyshev D.

Аннотация

The magnetic properties and Mossbauer spectra of amorphous 2NSR alloy samples are investigated after quenching and after tempering for different times at 520°C. After quenching, the alloy is inhomogeneous. Tempering of alloy samples below the crystallization temperature (540°C) raises the Curie temperature and the mean superfine field at the iron nuclei. Tempering leads to complex changes in the saturation magnetization. The changes in magnetic properties are analyzed.

Steel in Translation. 2016;46(8):606-608
pages 606-608 views