Hydroconversion of Vacuum Residue of a Blend of Western Siberian Oils in the Presence of Ex Situ Synthesized Suspensions of Nanosized Catalysts
- Авторы: Kadiev K.M.1, Gyul’maliev A.M.1, Zekel’ L.A.1, Kadieva M.K.1, Dandaev A.U.1, Batov A.E.1, Visaliev M.Y.1
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Учреждения:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Выпуск: Том 59, № Suppl 1 (2019)
- Страницы: S37-S44
- Раздел: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/181036
- DOI: https://doi.org/10.1134/S0965544119130061
- ID: 181036
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Аннотация
Concentrated suspensions of nanosized МоS2, МоS2+Ni7S6, Ni7S6, Fe1– xS, and (NH4)0.25 · WO3 particles with an average size of 273–364 nm have been synthesized from reverse emulsions of aqueous solutions of molybdenum, nickel, iron, and tungsten salts in the presence of a sulfiding agent and hydrogen in oil vacuum distillation residues and tested in oil vacuum distillation residue hydroconversion running in an autoclave and a pilot flow system. The test results have shown that the highest activity in hydrogenolysis reactions is exhibited by Mo-containing catalysts. The kinetic characteristics have been determined; the heat of the hydroconversion process has been calculated.
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Об авторах
Kh. Kadiev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
A. Gyul’maliev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
L. Zekel’
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
M. Kadieva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
A. Dandaev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
A. Batov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
M. Visaliev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: zekel@ips.ac.ru
Россия, Moscow, 119991
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