Deep Purification of Vacuum Gas Oil by the Method of Oxidative Desulfurization


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The possibility of using of the catalytic system based on formic acid and a transition metal salt in the presence of hydrogen peroxide for desulfurization of nonhydrotreated vacuum gas oil has been explored. Conditions for effective oxidation of organic sulfur compounds and maximal extraction of oxidized compounds from the feedstock have been selected. It has been shown that the catalysts based on tungsten salts are the most effective those for oxidative desulfurization of heavy feedstock. Under optimum conditions, the degree of desulfurization of vacuum gas oil was 89%.

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A. Akopyan

Faculty of Chemistry, Moscow State University

编辑信件的主要联系方式.
Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

D. Plotnikov

Faculty of Chemistry, Moscow State University

Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

P. Polikarpova

Faculty of Chemistry, Moscow State University

Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

A. Kedalo

Faculty of Chemistry, Moscow State University

Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

S. Egazar’yants

Faculty of Chemistry, Moscow State University

Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

A. Anisimov

Faculty of Chemistry, Moscow State University

Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

E. Karakhanov

Faculty of Chemistry, Moscow State University

Email: arvchem@yandex.ru
俄罗斯联邦, Moscow, 119991

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