Amine-Containing Acetylene Compounds of the Norbornene Series—Promising Biocides for Use in Petroleum Production


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A series of propargylamine derivatives possessing bactericidal activity against sulfate-reducing bacteria has been synthesized on the basis of bicyclo[2.2.1]hept-5-ene-2-yl-methylamine. It has been shown that in the case of interaction of aminated norbornene with propargyl bromide, corresponding adducts of the norbornene series which contain a terminal acetylene bond and an amino group in the side chain are formed depending on the molar ratio. Synthesized N-propargylbicyclo[2.2.1]hept-5-ene-2-yl-methylamine is a very reactive compound and can participate in various reactions, in particular, by the amino group or the double bond, to form new derivatives. It has been found that all the synthesized substances at their concentration of 500 mg/L fully inhibit the growth of sulfate-reducing bacteria.

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M. Shatirova

Institute of Polymer Materials, National Academy of Sciences of Azerbaijan

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Email: mshatirova@mail.ru
阿塞拜疆, Sumgayit, AZ 5004

M. Movsumzade

Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan

Email: avdeevavdeev@mail.ru
阿塞拜疆, Baku, AZ 1029

U. Dzhafarova

Kuliev Institute of Chemistry of Additives, National Academy of Sciences of Azerbaijan

Email: avdeevavdeev@mail.ru
阿塞拜疆, Baku, AZ 1029

Ya. Avdeev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

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Email: avdeevavdeev@mail.ru
俄罗斯联邦, Moscow, 119071

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