Email this article Distribution of Paraffin Hydrocarbons and Asphaltenes in Acidic Water-Oil Emulsion
- Authors: Ganeeva Y.M.1,2, Barskaya E.E.1,2, Okhotnikova E.S.1,2, Yusupova T.N.1,2, Davletshina L.F.3, Gus’kova I.A.4
-
Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
- Institute of Geology and Oil and Gas Technologies, Kazan State University
- Gubkin Russian State University of Oil and Gas
- Almet’evsk State Institute of Petroleum
- Issue: Vol 58, No 12 (2018)
- Pages: 1099-1106
- Section: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/180559
- DOI: https://doi.org/10.1134/S0965544118100055
- ID: 180559
Cite item
Open Access
Access granted
Subscription Access
Abstract
Asphaltenes and solid paraffins isolated from various layers of acidic water-oil emulsions obtained by mixing an oilfield emulsion with 15% solutions of hydrochloric and sulfamic acids with or without addition of Fe(III) have been studied by elemental analysis, IR and EPR spectroscopy, gas–liquid chromatography, and calorimetry. In acidic water-oil emulsions, the high-molecular-weight petroleum components have not been found to concentrate at the oil/water interface; however, a change in their composition has been revealed, which is more pronounced in the presence of Fe(III). The formation of diamagnetic complexes of the paramagnetic centers of asphaltenes with Fe(III) has been detected.
About the authors
Yu. M. Ganeeva
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center,Russian Academy of Sciences; Institute of Geology and Oil and Gas Technologies, Kazan State University
Author for correspondence.
Email: ganeeva@iopc.ru
Russian Federation, Kazan, Tatarstan; Kazan, Tatarstan
E. E. Barskaya
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center,Russian Academy of Sciences; Institute of Geology and Oil and Gas Technologies, Kazan State University
Email: ganeeva@iopc.ru
Russian Federation, Kazan, Tatarstan; Kazan, Tatarstan
E. S. Okhotnikova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center,Russian Academy of Sciences; Institute of Geology and Oil and Gas Technologies, Kazan State University
Email: ganeeva@iopc.ru
Russian Federation, Kazan, Tatarstan; Kazan, Tatarstan
T. N. Yusupova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center,Russian Academy of Sciences; Institute of Geology and Oil and Gas Technologies, Kazan State University
Email: ganeeva@iopc.ru
Russian Federation, Kazan, Tatarstan; Kazan, Tatarstan
L. F. Davletshina
Gubkin Russian State University of Oil and Gas
Email: ganeeva@iopc.ru
Russian Federation, Moscow
I. A. Gus’kova
Almet’evsk State Institute of Petroleum
Email: ganeeva@iopc.ru
Russian Federation, Almet’evsk, Tatarstan, 423450
Supplementary files
