Hydrogenation of Aromatic Substrates over Dispersed Ni–Mo Sulfide Catalysts in System H2O/CO

Abstract

The activity of unsupported Ni–Mo sulfide catalysts formed during the in situ decomposition of oil-soluble precursors (molybdenum hexacarbonyl, nickel naphthenate) in the hydrogenation of aromatic and naphthene-aromatic compounds is studied. The catalysts are characterized by HRTEM and XPS. Catalytic experiments are conducted at temperatures of 340–380°C and an increased pressure of ?? in the presence of water providing the in situ generation of hydrogen via the water-gas shift reaction. The catalysts exhibit a high activity in the hydrogenation of model substrates (methyl- and dimethyl-substituted naphthalenes and anthracene).