Email this article Direct conversion of ethanol and fusel oils to alkane–aromatic hydrocarbons in the presence of a pilot Pd–Zn/TsVM catalyst
- Authors: Chistyakov A.V.1,2, Tsodikov M.V.1,2, Chudakova M.V.1, Gubanov M.A.1, Zharova P.A.1,2, Bukina Z.M.1, Kolesnichenko N.V.1, Gekhman A.E.2,3, Khadzhiev S.N.1
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis
- Moscow Institute of Physics and Technology (State University)
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 58, No 1 (2018)
- Pages: 32-42
- Section: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/179996
- DOI: https://doi.org/10.1134/S096554411801005X
- ID: 179996
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Abstract
The conversion of ethanol and fusel oils to a С3–С12 alkane–aromatic fraction with high activity and selectivity in the presence of the Pd–Zn/TsVM pilot catalyst has been demonstrated. It has been shown that the ethanol conversion to alkanes and aromatic hydrocarbons in the presence of this catalyst proceeds by various routes to give ethylene and diethyl ether as intermediate products providing a 90–95% yield on the converted ethanol carbon basis for the target С3–С12 fraction containing up to 40% of branched alkanes.
About the authors
A. V. Chistyakov
Topchiev Institute of Petrochemical Synthesis; Moscow Institute of Physics and Technology (State University)
Author for correspondence.
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow; Dolgoprudnyi, Moscow oblast
M. V. Tsodikov
Topchiev Institute of Petrochemical Synthesis; Moscow Institute of Physics and Technology (State University)
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow; Dolgoprudnyi, Moscow oblast
M. V. Chudakova
Topchiev Institute of Petrochemical Synthesis
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow
M. A. Gubanov
Topchiev Institute of Petrochemical Synthesis
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow
P. A. Zharova
Topchiev Institute of Petrochemical Synthesis; Moscow Institute of Physics and Technology (State University)
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow; Dolgoprudnyi, Moscow oblast
Z. M. Bukina
Topchiev Institute of Petrochemical Synthesis
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow
N. V. Kolesnichenko
Topchiev Institute of Petrochemical Synthesis
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow
A. E. Gekhman
Moscow Institute of Physics and Technology (State University); Kurnakov Institute of General and Inorganic Chemistry
Email: chistyakov@ips.ac.ru
Russian Federation, Dolgoprudnyi, Moscow oblast; Moscow
S. N. Khadzhiev
Topchiev Institute of Petrochemical Synthesis
Email: chistyakov@ips.ac.ru
Russian Federation, Moscow
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