Influence of alkylation parameters, feedstock composition, and catalyst type on the ortho/para ratio of resulting alkylphenols


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Abstract

It has been found that process time and temperature affect the isomer ratio of alkylphenols depending on the catalyst type. Phenol alkylation with linear α-olefins leads a prevalence of ortho-alkylphenols over the para-isomers, unlike the case of branched olefins.

About the authors

S. V. Kotov

Middle Volga Oil Refining Research Institute

Author for correspondence.
Email: secr@svniinp.ru
Russian Federation, Novokuibyshevsk, Samara oblast, 446200

V. A. Tyshchenko

Middle Volga Oil Refining Research Institute

Email: nkzmip@nzmp.ru
Russian Federation, Novokuibyshevsk, Samara oblast, 446200

I. M. Zerzeva

Novokuibyshevsk Lubricants and Additives Plant

Author for correspondence.
Email: nkzmip@nzmp.ru
Russian Federation, Novokuibyshevsk, Samara oblast, 446207

A. V. Tarasov

Novokuibyshevsk Lubricants and Additives Plant

Email: nkzmip@nzmp.ru
Russian Federation, Novokuibyshevsk, Samara oblast, 446207

G. V. Timofeeva

Middle Volga Oil Refining Research Institute

Email: nkzmip@nzmp.ru
Russian Federation, Novokuibyshevsk, Samara oblast, 446200

N. S. Kotova

Middle Volga Oil Refining Research Institute

Email: nkzmip@nzmp.ru
Russian Federation, Novokuibyshevsk, Samara oblast, 446200

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