Email this article Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins
- Authors: Abdullaev M.G.1, Gebekova Z.G.2
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Affiliations:
- Dagestan State University
- lagestan State Pedagogical University
- Issue: Vol 56, No 2 (2016)
- Pages: 146-150
- Section: Article
- URL: https://journals.rcsi.science/0965-5441/article/view/178440
- DOI: https://doi.org/10.1134/S096554411602002X
- ID: 178440
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Abstract
Hydrogenation of aromatic nitro compounds to the corresponding amines on palladium-containing anion-exchange resins has been studied under mild conditions. It has been found that stericity has a significant effect on the activity and selectivity of the hydrogenation reaction. High efficiency of the palladium-containing anion-exchange resins in the synthesis of aromatic amines has been demonstrated. Halonitrobenzenes undergo intense dehalogenation resulting in a low yield of the corresponding amine.
About the authors
M. G. Abdullaev
Dagestan State University
Author for correspondence.
Email: mahram-ivgu@rambler.ru
Russian Federation, ul. Gadzhieva 43a, Makhachkala, Dagestan, 367025
Z. G. Gebekova
lagestan State Pedagogical University
Email: mahram-ivgu@rambler.ru
Russian Federation, ul. Yaragskogo 57, Makhachkala, Dagestan, 367003
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