The Effects of Cellulose Ethers and Limestone Fillers in Portland Cement-Based Mortars by 1H NMR relaxometry
- 作者: Jumate E.1, Moldovan D.1, Manea D.1, Demco D.1,2, Fechete R.1
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隶属关系:
- Technical University of Cluj-Napoca
- DWI-Leibniz-Institute for Interactive Materials, e.V., RWTH-Aachen University
- 期: 卷 47, 编号 12 (2016)
- 页面: 1353-1373
- 栏目: Original Paper
- URL: https://journals.rcsi.science/0937-9347/article/view/247613
- DOI: https://doi.org/10.1007/s00723-016-0844-y
- ID: 247613
如何引用文章
详细
The effect of cellulose ethers (CE) and limestone filler added in nowadays receipts to improve some thermal and hygroscopic properties of construction materials based on plaster mortar were evaluated by 1H 1D nuclear magnetic resonance (NMR) T2-distributions, distribution of pore size distribution, scanning electron microscopy images and compressive testing. The CE polymer is used in three concentrations of 0.5, 1.0 and 2.0 % from cement mass, and the limestone filler was used into a fixed concentration of 10 % from cement mass. The 1H 1D NMR Carr-Purcell-Meiboom-Gill decays measured for all samples were analyzed by inverse Laplace transform leading to a series of T2-distributions generally characterized by four peaks associated, from low to high T2-values, with bound water to cement components, and then with small, medium and large pores. A series of measurements were performed at 28 days after sample preparation, and then the samples were stored for 2 months in water in order for the pores to be saturated and measured again. From the 1H 1D NMR T2-distributions, into a spherical pores approximation, the distributions of pores sizes were calculated and characterized. For all samples a series of SEM images were recorded with different magnitudes and which, in particular were used to estimate the surface relaxivity factor used in the determination of pores distributions. We estimate the effect of CE polymer and limestone filler on the compression rate which was also correlated with the bound water percentage.
作者简介
Elena Jumate
Technical University of Cluj-Napoca
Email: rfechete@phys.utcluj.ro
罗马尼亚, Memorandumului 28, Cluj-Napoca, 400114
Dumitriţa Moldovan
Technical University of Cluj-Napoca
Email: rfechete@phys.utcluj.ro
罗马尼亚, Memorandumului 28, Cluj-Napoca, 400114
Daniela Manea
Technical University of Cluj-Napoca
Email: rfechete@phys.utcluj.ro
罗马尼亚, Memorandumului 28, Cluj-Napoca, 400114
Dan Demco
Technical University of Cluj-Napoca; DWI-Leibniz-Institute for Interactive Materials, e.V., RWTH-Aachen University
Email: rfechete@phys.utcluj.ro
罗马尼亚, Memorandumului 28, Cluj-Napoca, 400114; Forckenbeckstraße 50, Aachen, 52074
Radu Fechete
Technical University of Cluj-Napoca
编辑信件的主要联系方式.
Email: rfechete@phys.utcluj.ro
罗马尼亚, Memorandumului 28, Cluj-Napoca, 400114