63,65Cu NQR Spectra and Spin–Lattice Relaxation in Thermoelectric CuAlO2


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Abstract

The 63,65Cu nuclear quadrupole resonance spectra and spin–lattice relaxation rate (1/T1) have been measured in the semiconductor compound CuAlO2. The value of the nuclei quadrupole interaction constant QCC = 56.24(6) MHz (T = 298 K) has been obtained. The broad maximum has been found in the temperature dependence of 1/T1 in the low-temperature region (below 276 K). This maximum can be associated with the presence of energy levels in the forbidden band. The activation energy has been estimated in CuAlO2 [EA = 45(2) meV], assuming the activation character of the mobility of holes.

About the authors

V. V. Ogloblichev

M.N. Miheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences

Email: matukhinvl@mail.ru
Russian Federation, Yekaterinburg, 620108

V. L. Matukhin

Kazan State Power Engineering University

Author for correspondence.
Email: matukhinvl@mail.ru
Russian Federation, Kazan, 420066

I. Yu. Arapova

M.N. Miheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences

Email: matukhinvl@mail.ru
Russian Federation, Yekaterinburg, 620108

C. V. Schmidt

Kazan State Power Engineering University

Email: matukhinvl@mail.ru
Russian Federation, Kazan, 420066

R. R. Khusnutdinov

Kazan State Power Engineering University

Email: matukhinvl@mail.ru
Russian Federation, Kazan, 420066


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