Investigation of Polymer Degradation Using NMR Relaxometry with Inverse Laplace Transformation


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Abstract

In this work, the distributions of spin–lattice and spin–spin relaxation times of nuclear magnetic resonance are used to characterize the mobility of different parts of the polymer macromolecules and to analyze the crosslink density of the polymer chains. A change in the distribution of relaxation times is applied to detect the changes of the polymers quality caused by the influence of ozone, ultraviolet radiation, temperature cycling, and stretching deformation.

About the authors

A. Bogaychuk

Immanuel Kant Baltic Federal University

Email: n_sinyavsky@mail.ru
Russian Federation, A. Nevsky St. 14, Kaliningrad, 236041

N. Sinyavsky

Immanuel Kant Baltic Federal University; Kaliningrad State Technical University; Department of Physics and Chemistry, Baltic Fishing Fleet State Academy, Kaliningrad State Technical University

Author for correspondence.
Email: n_sinyavsky@mail.ru
ORCID iD: 0000-0003-1285-206X
Russian Federation, A. Nevsky St. 14, Kaliningrad, 236041; Sovietsky Prospect 1, Kaliningrad, 236022; Molodezhnaya St. 6, Kaliningrad, 236029

G. Kupriyanova

Immanuel Kant Baltic Federal University

Email: n_sinyavsky@mail.ru
Russian Federation, A. Nevsky St. 14, Kaliningrad, 236041


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