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Measurements of Adsorption and Thermal Deformations of Microporous Carbon Adsorbents


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Abstract

Adsorption-induced deformation of microporous carbon adsorbents AUK and AR-V with different genesis was measured in conditions of methane adsorption (temperature 273, 313, 353, 393 K; pressure 0–6 MPa). Thermal deformation of carbon adsorbents AUK and AR-V was measured in the temperature range of 273–573 K. Coefficients of linear thermal expansion (CTE) of carbon adsorbents were calculated in the temperature range of 273–573 K: for AUK, aT = (3 ± 0.15)·10–6 K–1; for AR-V, T = (8.4 ± 0.6)·10–5 K–1. A comparative analysis of the CTE of adsorbents and crystal graphite was implemented.

About the authors

I. E. Men’shchikov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Author for correspondence.
Email: i.menschikov@mail.ru
Russian Federation, Moscow

A. V. Shkolin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Email: i.menschikov@mail.ru
Russian Federation, Moscow

A. A. Fomkin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IFKhE RAN)

Email: i.menschikov@mail.ru
Russian Federation, Moscow

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