Coupled electroreduction of CO2 and H+ in the presence of substituted salts of 2,2'-bipyridine

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

The possibility of conjugate electroreduction of carbon dioxide and hydrogen in the presence of 2,2'-bipyridine and its N -substituted salts in the presence of acids with different pKa values was studied. It was revealed how the strength of the acid affects the efficiency of the process; in particular, it was determined that the presence of methylsulfonic acid in the system promotes the conjugate formation of hydrogen and the reduction of carbon dioxide to formic acid. Probable mechanisms for the reactions occurring have been proposed.

Sobre autores

E. Okina

National Research Ogarev Mordovia State University

L. Klimaeva

National Research Ogarev Mordovia State University

Email: l_klimaeva@mail.ru

D. Chugunov

National Research Ogarev Mordovia State University

S. Kostryukov

National Research Ogarev Mordovia State University

A. Kozlov

National Research Ogarev Mordovia State University

O. Tarasova

National Research Ogarev Mordovia State University

A. Yudina

National Research Ogarev Mordovia State University

Bibliografia

  1. Jenkinson D.S., Adams D.E., Wild A. Nature. 1991, 351. 304-306. doi: 10.1038/351304a0
  2. Weimer T., Schaber K., Specht M., Bansi A. Energy Convers. Manag. 1996, 370020, 1351-1356. doi: 10.1016/0196-8904(95)00345-2
  3. Liu J.-L., Wang X., Li X.-S., Likozar B., Zhu A.-M. J. Phys. D Appl. Phys. 2020, 53, 253001. doi: 10.1088/1361-6463/ab7c04
  4. Jessop P.G., Jo� F., Tai C.-C. Coord. Chem. Rev. 2004, 248, 2425-2442. doi: 10.1016/j.ccr.2004.05.019
  5. Glockler G. Phys. Chem. 1958, 62, 1049-1054. doi: 10.1021/j150567a006
  6. Tanaka K. BCSJ. 1998, 71, 17-29. doi: 10.1246/bcsj.71.17
  7. Ren S., Jouli� D., Salvatore D., Torbensen K., Wang M., Robert M., Berlinguette C.P. Science. 2019, 365, 367-369. doi: 10.1126/science.aax4608
  8. Jin S., Hao Z., Zhang K., Yan Z., Chen J. Angew. Chem. 2021, 133, 20795-20816. doi: 10.1002/ange.202101818
  9. Zhu D.D., Liu J.L., Qiao S.Z. Adv. Mater. 2016, 28, 3423-3452. doi: 10.1002/adma.201504766
  10. Alberico E., Nielsen M. Chem. Commun. 2015, 51, 6714-6725. doi: 10.1039/C4CC09471A
  11. Dong K. Razzaq R., Hu Y., Ding K. Top Curr. Chem. 2017, 375, 23. doi: 10.1007/s41061-017-0107-x
  12. Qiao J., Liu Y., Hong F., Zhang J. Chem. Soc. Rev. 2014, 43, 631-675. doi: 10.1039/C3CS60323G
  13. Zheng Y., Vasileff A., Zhou X., Jiao Y., Jaroniec M., Qiao S.-Z. J. Am. Chem. Soc. 2019, 141, 7646-7659. doi: 10.1021/jacs.9b02124
  14. Boutin E., Robert M. Trends Chem. 2021, 3, 359-372. doi: 10.1016/j.trechm.2021.02.003
  15. Lim R. J., Xie M., Sk M.A., Lee J.-M., Fisher A., Wang X., Lim K.H. Catal. Today. 2014, 233, 169-180. doi: 10.1016/j.cattod.2013.11.037
  16. Specht M., Staiss F., Bandi A., Weimer T. Int. J. Hydrog. Energy. 1998, 23, 387-396. doi: 10.1016/S0360-3199(97)00077-3

Declaração de direitos autorais © Russian Academy of Sciences, 2023

Este site utiliza cookies

Ao continuar usando nosso site, você concorda com o procedimento de cookies que mantêm o site funcionando normalmente.

Informação sobre cookies