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Synthesis of MONO- and BIS-Polyfluoroalcholate Derivatives Containing Aryl Ethers and Thioethers
- Authors: Soboleva E.A.1, Shelkovnikov V.V.1,2, Chernonosov A.A.3
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Affiliations:
- Novosibirsk Institute of Organic Chemistry im. Vorozhtsova, Siberian Branch Russian Academy of Sciences
- Novosibirsk State Technical University
- Institute of Chemical Biology and Fundamental Medicine, Siberian Branch Russian Academy of Sciences
- Issue: Vol 61, No 10 (2025)
- Pages: 1503-1513
- Section: ЭКСПЕРИМЕНТАЛЬНЫЕ СТАТЬИ
- URL: https://journals.rcsi.science/0514-7492/article/view/380887
- DOI: https://doi.org/10.7868/S3034630425100126
- ID: 380887
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Abstract
A series of p-substituted tetrafluoroaldehydes and ketones were obtained by the interaction of pentafluoroacetophenone and pentafluorobenzaldehyde with an excess of 4,4'-thiobisthiophenol, 4,4'-thiobisphenol and tert-butylthiophenol. The use of a twofold excess of pentafluoroacetophenone and pentafluorobenzaldehyde in the reaction with respect to 4,4'-thiobisthiophenol and 4,4'-thiobisphenol leads to the formation of bis-octafluoroaldehydes and ketones in high yields. New mono- and bis-polyfluoroalcoholanes containing aryl ethers and thioethers and capable of further modifications were synthesized on the basis of mono- and bis-substituted aldehydes and ketones.
About the authors
E. A. Soboleva
Novosibirsk Institute of Organic Chemistry im. Vorozhtsova, Siberian Branch Russian Academy of Sciences
Email: lena9618745603@yandex.ru
ORCID iD: 0009-0009-2633-5734
Novosibirsk, Russia
V. V. Shelkovnikov
Novosibirsk Institute of Organic Chemistry im. Vorozhtsova, Siberian Branch Russian Academy of Sciences; Novosibirsk State Technical University
ORCID iD: 0009-0001-3364-668X
Novosibirsk, Russia; Novosibirsk, Russia
A. A. Chernonosov
Institute of Chemical Biology and Fundamental Medicine, Siberian Branch Russian Academy of Sciences
ORCID iD: 0000-0001-8362-2443
Novosibirsk, Russia
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