A New Approach to the Synthesis of Dialkyl(Trimethylsilyl)Phosphites

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Abstract

Dialkyl (trimethylsilyl) phosphites of various structures were synthesized in high yields (87–92%) by the interaction of dialkyl phosphites of various structures with hexamethyldisilazane at 20°C and in the presence of ZnCl2 . The reaction is completed in 0.5 hours and does not require the use of specially prepared solvents 2 or an inert atmosphere. The initial hydrophosphites were synthesized by the transesterification reaction of dimethylphosphite with alcohols in the presence of 0.5 mol.% ZnSO4 at 110–120°C. 4

About the authors

V. P. Morgalyuk

Federal state budgetary institution of science "A. N. Nesmeyanov Institute of Organoelement Compounds", Russian Academy of Sciences

Email: morgaliuk@mail.ru
ORCID iD: 0000-0001-9845-549X
ul. Vavilova 28, Moscow, 119991, Russia

T. V. Strelkova

Federal state budgetary institution of science "A. N. Nesmeyanov Institute of Organoelement Compounds", Russian Academy of Sciences

Email: morgaliuk@mail.ru
ORCID iD: 0000-0002-3485-2936
ul. Vavilova 28, Moscow, 119991, Russia

R. U. Takazova

Federal state budgetary institution of science "A. N. Nesmeyanov Institute of Organoelement Compounds", Russian Academy of Sciences

Email: morgaliuk@mail.ru
ORCID iD: 0000-0003-3945-9233
ul. Vavilova 28, Moscow, 119991, Russia

A. G. Buyanovskaya

Federal state budgetary institution of science "A. N. Nesmeyanov Institute of Organoelement Compounds", Russian Academy of Sciences

Email: morgaliuk@mail.ru
ORCID iD: 0000-0003-4963-3979
ul. Vavilova 28, Moscow, 119991, Russia

V. K. Brel

Federal state budgetary institution of science "A. N. Nesmeyanov Institute of Organoelement Compounds", Russian Academy of Sciences

Email: morgaliuk@mail.ru
ORCID iD: 0000-0003-4645-3251
ul. Vavilova 28, Moscow, 119991, Russia

References

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