New Bifunctional Chalcogenorganic Compounds Based on Reactions of Tellurium, Selenium, and Sulfur Halides with Allylicatic Acid

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Abstract

Based on the chalcogenfunctionalization reactions of allylicatic acid with tellurium, selenium, and sulfur halides, methods for the synthesis of new bifunctional chalcogenorganic compounds with yields of 86–99 % have been developed. The reactions of sulfur and selenium dihalides yield chalcogenides containing two butyrolactone rings in 97–99 % yields. Reactions with TeCl4 and TeBr4 yield trihalogenetellanes with a methylbutyrolactone group. The interaction of TeBr4 with allylicatic acid in methanol proceeds as methoxytellurination and is accompanied by the transformation of the carboxyl group into a methoxycarbonyl group. Reduction of the trihalogenetellanes with high yields yielded the corresponding ditellurides.

About the authors

M. V. Musalova

A.E. Favorsky Irkutsk Institute of Chemistry, Federal Research Center, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0003-3619-7856
Irkutsk, Russia

M. V. Musalov

A.E. Favorsky Irkutsk Institute of Chemistry, Federal Research Center, Siberian Branch of the Russian Academy of Sciences

ORCID iD: 0000-0002-7638-8377
Irkutsk, Russia

A. A. Pakeeva

A.E. Favorsky Irkutsk Institute of Chemistry, Federal Research Center, Siberian Branch of the Russian Academy of Sciences

Irkutsk, Russia

L. A. Ivanova

A.E. Favorsky Irkutsk Institute of Chemistry, Federal Research Center, Siberian Branch of the Russian Academy of Sciences

Irkutsk, Russia

V. A. Potapov

A.E. Favorsky Irkutsk Institute of Chemistry, Federal Research Center, Siberian Branch of the Russian Academy of Sciences

Email: v.a.potapov@mail.ru
ORCID iD: 0000-0002-3151-6726
Irkutsk, Russia

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