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Unexpected Product of Allyl Hydroxylation During Ozone Degradation of N-Tosylate 2-(Cyclohex-1-en-1-yl)-6-methylaniline
- Authors: Safargalin R.R.1, Gataullin R.R.1
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Affiliations:
- Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
- Issue: Vol 61, No 4 (2025)
- Pages: 387–392
- Section: ЭКСПЕРИМЕНТАЛЬНЫЕ СТАТЬИ
- URL: https://journals.rcsi.science/0514-7492/article/view/307890
- DOI: https://doi.org/10.31857/S0514749225040043
- EDN: https://elibrary.ru/SDHLIF
- ID: 307890
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Abstract
During the ozonolysis of N-[(2-cyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide followed by the reduction of oxidation products with dimethyl sulfide, the expected ketoaldehyde—4-methyl-N-[2-methyl-6-(6-oxohexanoyl)phenyl]benzenesulfonamide—is formed, along with an unexpected allyl hydroxylation product—N-[2-(6-hydroxycyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide.
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About the authors
R. R. Safargalin
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of SciencesUfa, Russia
R. R. Gataullin
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: gataullin@anrb.ru
Ufa, Russia
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