Kinetics of Catalytic Oxidation of Oleic Acid Methyl Ester

D. Yu. Yhshchenko; Ющенко Д. Ю.; Z. P. Pai; Пай З. П.; U. V. Uchenova; Ученова Ю. В.; T. B. Khlebnikova; Хлебникова Т. Б.

doi:10.31857/S0453881123030127

Kinetics of Catalytic Oxidation of Oleic Acid Methyl Ester

Autores: Yhshchenko D.Y.¹, Pai Z.P.¹, Uchenova U.V.¹, Khlebnikova T.B.¹
Afiliações:
1. Boreskov Institute of Catalysis SB RAS
Edição: Volume 64, Nº 3 (2023)
Páginas: 298-304
Seção: ARTICLES
URL: https://journals.rcsi.science/0453-8811/article/view/136995
DOI: https://doi.org/10.31857/S0453881123030127
ID: 136995

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Resumo

The results of studying the kinetics of the reaction of catalytic oxidation of oleic acid methyl ester with hydrogen peroxide in a two-phase system (aqueous phase-organic phase) in the presence of a bifunctional catalyst of the composition [(Octⁿ)₃NMe]₃{PO₄[WO(O₂)₂]₄} are presented. For the selected reaction conditions, the first orders of catalyst, substrate and oxidizer are established. The value of the activation energy for the temperature range 313–353 K is 47 ± 3 kJ/mol, and the pre-exponential multiplier is (6.0 ± 0.3) × 10⁷ L² mol^–2 min^–1.

Palavras-chave

oleic acid, oleic acid methyl ester, epoxides, tungsten peroxocomplexes, hydrogen peroxide, homogeneous and heterogeneous catalysis

Bibliografia

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