Dry reforming of methane into synthesis gas on oxide catalysts Ni/CexSn1–xO2: effect of the template nature

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Abstract

The work is devoted to revealing the influence of the synthesis method, namely the nature of the template, on the catalytic properties of the supported Ni/CexSn1–xO2 systems in dry reforming of methane (DRM) in a flow system with a fixed catalyst bed. A comparison of the characteristics of catalysts obtained using different templates (ionic – cetyltrimethylammonium bromide (CTAB), non-ionic polymer Pluronic-123 (P123), biotemplate – pine sawdust) and containing cerium and tin in a molar ratio of Ce : Sn = 9:1 was carried out. The mass content of nickel was 3%. The catalysts were characterized by temperature-programmed reduction with hydrogen, X-ray diffraction, X-ray photoelectron spectroscopy, scanning and transmission electron microscopy with energy-dispersive X-ray analysis, and magnetometry. The systems obtained in the presence of the biotemplate and P123 were active in CDRM. The highest values of steady-state conversion of methane (11%) and carbon dioxide (29%) were provided by the Ni/CeO2–SnO2–P123 catalyst. Analysis of the results of physicochemical methods showed that the Ni/CeO2–SnO2–P123 sample has the most uniform distribution and increased dispersion of nickel particles. It was found that the use of the P123 polymer template contributes to the formation of a greater number of interaction centers of nickel with the tin-containing oxide phase in the Ni/CexSn1–xO2–P123. The nature of the template significantly affects the structural state of the active component and, as a consequence, the catalytic characteristics in DRM.

About the authors

I. Yu. Kaplin

Lomonosov Moscow State University

Email: kaplinigormsu@gmail.com
ORCID iD: 0000-0002-5091-6290
Moscow, Russia

A. A. Zorina

Lomonosov Moscow State University

Moscow, Russia

E. S. Lokteva

Lomonosov Moscow State University

ORCID iD: 0000-0003-3510-4822
Moscow, Russia

P. A. Chernavsky

Lomonosov Moscow State University; A.V. Topchiev Institute of Petrochemical Synthesis RAS; N.D. Zelinsky Institute of Organic Chemistry RAS

ORCID iD: 0000-0001-8443-8541
Moscow, Russia; Moscow, Russia; Moscow, Russia

E. V. Golubina

Lomonosov Moscow State University

ORCID iD: 0000-0002-1040-1428
Moscow, Russia

A. O. Kamaev

Lomonosov Moscow State University

ORCID iD: 0000-0002-6648-0647
Moscow, Russia

S. V. Maksimov

Lomonosov Moscow State University

ORCID iD: 0000-0002-0672-2683
Moscow, Russia

K. I. Maslakov

Lomonosov Moscow State University

Moscow, Russia

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