NI-CONTAINING GLASS-FIBER CATALYST FOR HYDROGENOLYSIS OF LIGHT PARAFFINS: RELATIONSHIP BETWEEN ACTIVITY AND CATALYST PREPARATION CONDITIONS

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Abstract

This study evaluates the efficiency of nickel-containing structured glass-fiber catalysts prepared by two different methods for the hydrogenolysis of saturated hydrocarbons, including propane, butane, and pentane. he dependence of the crystallite size and dispersion of the catalyst’s active component (AC) on the preparation method and reduction temperature conditions was established. Impulse surface thermosynthesis (ISTS) facilitates the most uniform distribution of the AC over the support surface and its higher dispersion. The crystallite size is primarily determined by the reduction temperature of the AC. The GFC containing ~10 wt % nickel, prepared by the ISTS method and reduced at the minimum temperature of 300°C, demonstrated the highest catalytic activity. Compared to a commercial nickel catalyst, the Ni/GFC samples exhibited tens of times higher specific catalytic activity per unit mass of nickel. Nickel-containing GFCs synthesized by the ISTS method are highly promising for use in advanced catalytic technologies for paraffin hydrogenolysis, particularly for processing gas condensate into methane.

About the authors

M. Sebaa

Tyumen State University

Email: m.sibaa@utmn.ru
address, Tyumen, 625003 Russia

V. B. Kharitontsev

Tyumen State University

address, Tyumen, 625003 Russia

N. A. Shulaev

Tyumen State University

address, Tyumen, 625003 Russia

E. A. Tissen

Tyumen State University

address, Tyumen, 625003 Russia

A. N. Zagoruyko

Tyumen State University; Boreskov Institute of Catalysis SB RAS

address, Tyumen, 625003 Russia; address, Novosibirsk, 630090 Russia

A. V. Elyishev

Tyumen State University

address, Tyumen, 625003 Russia

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