XPS STUDY OF DIFFERENCES IN STABILITY OF MWCNTS AND N-MWCNTS AS A SUPPORT FOR MODEL SILVER CATALYST FOR ETHYLENE EPOXIDATION

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The effect of preparation conditions on the stability of N-MWCNT samples prepared under oxygen-free conditions by the method of catalytic gas-phase decomposition of ethylene at 680°C on the Fe2Co/Al2O3 catalyst in the presence of NH3, with respect to atmospheric oxygen was studied by the XPS method. The analysis of the oxygen and nitrogen contents in the N-MWCNT composition, as well as the shape of the C1s XPS line after sample removal from the reactor in the air depending on the volume fraction of ammonia in the reaction mixture, as well as after treatment in nitric acid indicates that at low NH3 contents (2–4 vol. %) the incorporation of nitrogen into the structure of nanotubes leads to an increase in the structure ordering / a decrease in disorder, as a result, the oxygen content in these samples is minimal. Comparison of the supported catalysts Ag/MWCNT-0n and Ag/N-MWCNT-4n shows that the introduction of nitrogen during the support synthesis allows not only to decrease the oxygen content in carbon nanotubes, but also to increase the oxidation stability of both the support itself and the silver catalyst based on it.

Sobre autores

A. Ananina

Boreskov Institute of Catalysis SB RAS

ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

A. Nartova

Boreskov Institute of Catalysis SB RAS

Email: nartova@catalysis.ru
ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

R. Kvon

Boreskov Institute of Catalysis SB RAS

ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

A. Dmitrachkov

Boreskov Institute of Catalysis SB RAS

ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

M. Kazakova

Boreskov Institute of Catalysis SB RAS

ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

G. Golubtsov

Boreskov Institute of Catalysis SB RAS

ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

V. Bukhtiyarov

Boreskov Institute of Catalysis SB RAS

ave. Acad. Lavrentieva, 5, Novosibirsk, 630090 Russia

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