Study of deactivation of Mg-containing zeolite catalyst in propane conversion into olefinic hydrocarbons

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Abstract

The process of deactivation of magnesium-containing zeolite in three interregeneration cycles of operation during the conversion of propane into olefin hydrocarbons has been studied. The main factors leading to a decrease in the activity and selectivity of the catalyst have been identified. The distribution and state of active components in the catalytic system before and after the reaction, as well as after oxidative regeneration of the catalyst have been investigated. The nature and amount of carbon deposits formed on the catalyst under study during the reaction have been established, and their absence after its regeneration has been proven.

About the authors

A. A. Vosmerikov

Institute of Petroleum Chemistry SB RAS

Email: antonvosmerikov@gmail.com
Akademichesky ave., 4, Tomsk, 634055 Russia

Y. E. Barbashin

Institute of Petroleum Chemistry SB RAS

Akademichesky ave., 4, Tomsk, 634055 Russia

L. N. Vosmerikova

Institute of Petroleum Chemistry SB RAS

Akademichesky ave., 4, Tomsk, 634055 Russia

E. Y. Gerasimov

Federal Research Center, Boreskov Institute of Catalysis SB RAS

Acad. Lavrentieva ave, 5, Novosibirsk, 630090 Russia

A. V. Vosmerikov

Institute of Petroleum Chemistry SB RAS

Akademichesky ave., 4, Tomsk, 634055 Russia

References

  1. Khalil Y.P. Propylene in Demand: Roadblocks and Opportunitie, 2015. Available online: https://insights.globalspec.com/article/473/propylene-in-demand-roadblocks-and-opportunities
  2. Amghizar I., Vandewalle L.A., Van Geem K.M., Marin G.B. // Engineering. 2017. V. 3. P. 171.
  3. Liu S., Zhang B., Liu G. // React. Chem. Eng. 2021. V. 6. № 1. P. 9.
  4. Chen S., Chang X., Sun G., Zhang T., Xu Y., Wang Y., Pei C., Gong J. // Chem. Soc. Rev. 2021. V. 5. P. 3315.
  5. Liu S., Zhang B., Liu G. // React. Chem. Eng. 2021. V. 6. № 1. P. 9.
  6. Sattler J.J., Ruiz-Martinez J., Santillan-Jimenez E., Weckhuysen B.M. // Chem. Rev. 2014. V. 519. № 114. P. 10613.
  7. Левин В.О., Потехин В.М., Кудимова М.В. // Нефтепереработка и нефтехимия. Научно-технические достижения и передовой опыт. 2017. Т. 4. С. 28.
  8. Погосян Н.М., Погосян М.Д., Шаповалова О.В., Стрекова Л.Н. Тавадян Л.А., Арутюнов В.С. // Нефтегазохимия. 2016. Т. 2. С. 38.
  9. Восмерикова Л.Н., Восмериков А.А., Степанов А.А., Восмериков А.В. // Нефтегазохимия. 2024. № 3–4. С. 65.
  10. Vosmerikov A.A., Vosmerikova L.N., Barbashin Ya.E., Vosmerikov A.V. // J. Siberian Federal University. Chemistry. 2024. V. 17. № 3. P. 419.
  11. Gong J. // Chem. Soc. Rev. 2021. V. 50. P. 3315.
  12. Hu Z., Yang D., Wang Z., Yuan Z. // Chin. J. Catal. 2019. V. 40. P. 1233.
  13. Carrero C.A., Schloegl R., Wachs I.E., Schomaecker R. // ACS Catal. 2014. V. 4. P. 3357.
  14. Honeywell Successfully Commissions Second C3 Oleflex™ Unit for Zhejiang Satellite [электронный ресурс]. Сайт Honeywell, режим доступа: https://www.honey well.com/en-s/newsroom/pressreleases/ 2019/09/honeywell-successfully-commissions-second-c3-oleflex-unit-for-zhejiang-satellite (дата обращения: 02.06.2021)
  15. Sun M., Hu Z., Wang H., Suo Y., Yuan Z.-Y. // ACS Catal. 2023. V. 13. № 7. P. 4719.
  16. Wang W., Yao S., Deng S., Wang Y., Qiu C., Mao C., Wang J.G. // Langmuir. 2021. V. 37. P. 12529.
  17. Lian Z., Si C., Jan F., Zhi S., Li B. // ACS Catal. 2021. V. 11. P. 9279.
  18. Wang H.-Z., Sun L.-L., Sui Z.-J., Zhu Y.-A., Ye G.-H., Chen D., Zhou X.-G., Yuan W.-K. // Ind. Eng. Chem. Res. 2018. V. 57. P. 8647.
  19. Восмериков А.А., Восмерикова Л.Н., Восмериков А.В. // Известия высших учебных заведений. Серия: Химия и химическая технология. 2023. Т. 66. № 11. С. 42.
  20. Kalantari N., Farzi A., Hamooni F., Delibas N., Tarjomannejad A., Niaei A., Salari D. // J. SolGel Sci. Technol. 2024. P. 1‒20.
  21. He H., Anfeng Z., Limin R., Xiaowa N., Min L., Yi L., Chuan S., Hong Y., Chunshan S., Xinwen G. // Catal. Today. 2022. V. 252. Art. 117529.

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