New Catalyst Systems for the Polymerization of Norbornene and Its Derivatives Based on Cationic Palladium Cyclopentadienyl Complexes

D. S. Suslov; Суслов Д. С.; M. V. Pakhomova; Пахомова М. В.; M. V. Bykov; Быков М. В.; T. S. Orlov; Орлов Т. С.; Z. D. Abramov; Абрамов З. Д.; A. V. Suchkova; Сучкова А. В.; P. A. Abramov; Абрамов П. А.

doi:10.31857/S0453881124010058

New Catalyst Systems for the Polymerization of Norbornene and Its Derivatives Based on Cationic Palladium Cyclopentadienyl Complexes

Authors: Suslov D.S.¹^,2, Pakhomova M.V.¹^,2, Bykov M.V.¹^,2, Orlov T.S.²^,3, Abramov Z.D.¹^,2, Suchkova A.V.², Abramov P.A.⁴
Affiliations:
1. Irkutsk State University, Department of Chemistry
2. Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis
3. National Research Irkutsk State Technical University, School of High Technologies
4. Nikolaev Institute of Inorganic Chemistry SB RAS
Issue: Vol 65, No 1 (2024)
Pages: 48-66
Section: ARTICLES
URL: https://journals.rcsi.science/0453-8811/article/view/259676
DOI: https://doi.org/10.31857/S0453881124010058
EDN: https://elibrary.ru/GZYHZB
ID: 259676

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Abstract

The catalytic properties of systems based on [Pd(Cp)(L)_n]_m[BF₄]_m (where Cp = η⁵-^C₅H₅; n = 2, m = 1: L = tris(orthomethoxyphenyl)phosphine, triphenylphosphine, tris(2-furyl)phosphine (TFP), n = 1, m = 1: L = 1,1'-bis(diphenylphosphino)ferrocene, 1,3-bis(diphenylphosphino)propane, 1,4-bis(diphenylphosphino)butane, 1,5-bis(diphenylphosphino)pentane; n = 1, m = 2 or 3: L = 1,6-bis(diphenylphosphino)hexane) in the addition homoand copolymerization of norbornene (NB) and its derivatives have been studied. These complexes can be activated with the Lewis-acids (BF₃∙ OEt₂ or AlCl₃). The productivity of the [Pd(Cp)(PPh₃)₂][BF₄]/BF₃∙ OEt₂ catalyst system in the polymerization of norbornene is up to 188800 mol_NB mol_Pd^⁻¹^.The homopolymerization of 5-methoxycarbonylnorbornene and copolymerization of NB with 5-methoxycarbonylnorbornene or 5-phenylnorbornene were studied in the presence of BF₃∙ OEt₂ and [Pd(Cp)(L)₂][BF₄] (L = PPh₃ or TFP). A hypothesis for the catalyst’s formation via the intramolecular rearrangement of the η⁵-^Cp ligand into the η¹-^Cp form upon interaction with a Lewis acid is suggested. The structure of the [Pd(Cp)(TFP)2]BF₄ (I) was determined by X-ray diffraction. In the crystal structure of I, the palladium coordination sphere is characterized by a slight distortion of the square planar geometry of the central atom, and the cyclopentadiyl fragment is in an eclipsed conformation. Based on the XRD data, the steric hindrance of the TFP ligand was estimated (the cone angle is 149°).

Keywords

norbornene, cylopentadienyl, palladium, addition polymerization, boron trifluoride etherate

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