XPS Study of the Preparation of Single-Site Catalysts Based on Ir(I) and Rh(I) Complexes Immobilized on a SiO 2  Surface Using a P-Containing Linker

M. Yu. Smirnov; Смирнов М. Ю.; L. M. Kovtunova; Ковтунова Л. М.; A. V. Kalinkin; Калинкин А. В.; I. V. Skovpin; Сковпин И. В.; I. V. Koptyug; Коптюг И. В.; V. I. Bukhtiyarov; Бухтияров В. И.

doi:10.31857/S0453881123060175

XPS Study of the Preparation of Single-Site Catalysts Based on Ir(I) and Rh(I) Complexes Immobilized on a SiO₂ Surface Using a P-Containing Linker

Authors: Smirnov M.Y.¹, Kovtunova L.M.¹, Kalinkin A.V.¹, Skovpin I.V.², Koptyug I.V.², Bukhtiyarov V.I.¹
Affiliations:
1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences
2. International Tomography Center, Siberian Branch, Russian Academy of Sciences
Issue: Vol 64, No 6 (2023)
Pages: 837-852
Section: Articles
URL: https://journals.rcsi.science/0453-8811/article/view/231849
DOI: https://doi.org/10.31857/S0453881123060175
EDN: https://elibrary.ru/KXGITY
ID: 231849

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Abstract

Samples of model single-site iridium and rhodium catalysts were synthesized by immobilization of complexes [Ir(COD)(IMes)Cl] and [Rh(COD)(IMes)Cl], where COD is cyclooctadiene-1,5 and IMes is 1,3‑bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, on the surface of silicon dioxide modified with a linker containing diphenylphosphine group (Ph₂P). Silicon plates with a flat surface covered with a layer of natural oxide 1–3 nm thick, Si-SiO₂(nat), or with a specially grown SiO₂ film (∼300 nm), Si-SiO₂(ox), were used as supports. The chemical compositions of the surface of the modified silicon plates and samples of model catalysts were characterized by XPS. Based on these XPS studies, a tentative conclusion was made about the coordination of immobilized complexes to the SiO₂ surface. Catalyst samples were tested in the gas-phase hydrogenation of propene with parahydrogen.

Keywords

Ir(I) and Rh(I) complexes, SiO₂, single-center catalysts, X-ray photoelectron spectroscopy (XPS), hydrogenation of propene with parahydrogen

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