ELECTROCHMEICAL SYNTHESIS OF TUNGSTEN OXIDE IN CHLORIDE SOLUTIONS FOR ENVIRONMENTAL PHOTOCATALYSIS
- 作者: Ulyankina A.1, Tsarenko A.1, Molodtsova T.1, Fesenko L.1, Smirnova N.1
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隶属关系:
- Platov South-Russian State Polytechnic University (NPI)
- 期: 卷 59, 编号 12 (2023)
- 页面: 807-813
- 栏目: Articles
- URL: https://journals.rcsi.science/0424-8570/article/view/232692
- DOI: https://doi.org/10.31857/S0424857023120150
- EDN: https://elibrary.ru/QBXRWC
- ID: 232692
如何引用文章
详细
The electrochemical behavior of tungsten in chloride electrolytes with various cationic compositions (Na+, K+, Li+, NH4+) under pulse alternating current has been studied. The decisive influence of the nature of the electrolyte on the phase composition of the resulting dispersed products is shown. The use of NH4Cl ensures the formation of pure crystalline WO3 with a particle size of 30–35 nm. The photoelectrochemical activity of the synthesized WO3 in a sulfuric acid medium under simulated solar radiation has been studied. The addition of glycerol to H2SO4 causes a cathodic shift in the oxidation onset potential by 0.25 V and a threefold increase in the maximum photocurrent density. The possibility of using a WO3/FTO photoanode as part of a flow-through photocatalytic fuel cell (fuel - glycerol, air-breathing Pt/C cathode), characterized by excellent stability in an acidic environment and the maximum power density of 64.0 μW cm-2 is shown.
作者简介
A. Ulyankina
Platov South-Russian State Polytechnic University (NPI)
Email: anya-barbashova@yandex.ru
346428 Novocherkassk, Russia
A. Tsarenko
Platov South-Russian State Polytechnic University (NPI)
Email: anya-barbashova@yandex.ru
346428 Novocherkassk, Russia
T. Molodtsova
Platov South-Russian State Polytechnic University (NPI)
Email: anya-barbashova@yandex.ru
346428 Novocherkassk, Russia
L. Fesenko
Platov South-Russian State Polytechnic University (NPI)
Email: anya-barbashova@yandex.ru
346428 Novocherkassk, Russia
N. Smirnova
Platov South-Russian State Polytechnic University (NPI)
编辑信件的主要联系方式.
Email: anya-barbashova@yandex.ru
346428 Novocherkassk, Russia
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