SYNTHESIS AND PPOPERTIES OF ZNO/ZNWO4 NANOCOMPOSITES FOR PHOTOELECTROCHEMICAL APPLICATIONS:

A. A. Ulyankina; Ульянкина А. А.; A. D. Tsarenko; Царенко А. Д.; T. A. Molodtsova; Молодцова Т. А.; M. V. Gorshenkov; Горшенков М. В.; N. V. Smirnova; Смирнова Н. В.

doi:10.31857/S0424857023120149

Нанокомпозиты ZnO/ZnWO₄ для фотоэлектрохимических приложений: синтез и свойства

Авторы: Ульянкина А.А.¹, Царенко А.Д.¹, Молодцова Т.А.¹, Горшенков М.В.², Смирнова Н.В.¹
Учреждения:
1. Южно-Российский государственный политехнический университет (НПИ) им. М.И. Платова
2. Национальный исследовательский технологический университет “МИСИС”
Выпуск: Том 59, № 12 (2023)
Страницы: 790-797
Раздел: Статьи
URL: https://journals.rcsi.science/0424-8570/article/view/232690
DOI: https://doi.org/10.31857/S0424857023120149
EDN: https://elibrary.ru/VDTVFT
ID: 232690

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Аннотация

Получена серия нанокомпозитов ZnO/ZnWO₄ с различным содержанием фазы ZnWO₄ на основе нанопорошков ZnO и WO₃, электрохимически синтезированных под действием переменного импульсного тока. Комплексом физико-химических методов (рентгенофазовый анализ, спектроскопия комбинационного рассеяния, просвечивающая электронная микроскопия, энергодисперсионный микроанализ) исследованы состав и структурные характеристики полученных материалов. Определен оптимальный состав нанокомпозита с содержанием ZnWO₄ ~ 6% для использования в качестве фотоанодного материала проточного фототопливного элемента с сульфатным электролитом с добавлением органического и неорганического топлива. Максимальные значения E_oc и P_max, которые составили 850 мВ и 85.8 мкВт/см² соответственно, были достигнуты при использовании Na₂SO₄ c добавлением глюкозы в качестве топлива.

Ключевые слова

ZnO/ZnWO₄, нанокомпозит, фотоэлектрохимическая активность, фототопливный элемент

Список литературы

Isaev, A.B., Shabanov, N.S., Sobola, D., Kaviyarasu, K., Ismailov, A.M., and Omarov, G.M., ZnO/Chalcogenides Semiconductor Heterostructures for Photoelectrochemical Water Splitting, in Nanomaterials for Energy Conversion, Biomedical and Environmental Applications, Kasinathan, K., Elshikh, M.S., and Al Farraj, D.A.-A., Editors. 2022, Singapore: Springer Nature, p. 3-35. https://doi.org/10.1007/978-981-19-2639-6_1
Grinberg, V.A., Emets, V.V., Maiorova, N.A., Maslov, D.A., Averin, A.A., Polyakov, S.N., Molchanov, S.P., Levin, I.S., and Tsodikov, M.V., Photoelectrochemical Activity of Nanosized Titania, Doped with Bismuth and Lead, in Visible Light Region, Prot. Met. Phys. Chem. Surf., 2019, vol 55, p. 55. https://doi.org/10.1134/S207020511901012X
Kageshima, Y., Wada, H., Teshima, K., and Nishikiori, H., Hydrogen evolution and electric power generation through photoelectrochemical oxidation of cellulose dissolved in aqueous solution, Appl. Catal. B: Environ., 2023, vol. 327, p. 122431. https://doi.org/10.1016/j.apcatb.2023.122431
Ismael, M., Latest progress on the key operating parameters affecting the photocatalytic activity of TiO2-based photocatalysts for hydrogen fuel production: A comprehensive review, Fuel, 2021, vol. 303, p. 121207. https://doi.org/10.1016/j.fuel.2021.121207
Molodtsova, T., Gorshenkov, M., Kolesnikov, E., Leontyev, I., Kaichev, V., Zhigunov, D., Faddeev, N., Kuriganova, A., and Smirnova, N., Fabrication of nano-In2O3 phase junction by pulse alternating current synthesis for enhanced photoelectrochemical performance: Unravelling the role of synthetic conditions, Ceram. Int., 2023, vol. 49, p. 10986. https://doi.org/10.1016/j.ceramint.2022.11.293
Tsarenko, A., Gorshenkov, M., Yatsenko, A., Zhigunov, D., Butova, V., Kaichev, V., and Ulyankina, A., Electrochemical Synthesis-Dependent Photoelectrochemical Properties of Tungsten Oxide Powders, Chem Engineering, 2022, vol. 62, p. 31. https://doi.org/10.3390/chemengineering6020031
Mika, K., Syrek, K., Uchacz, T., Sulka, G.D., and Zaraska, L., Dark nanostructured ZnO films formed by anodic oxidation as photoanodes in photoelectrochemical water splitting, Electrochim. Acta, 2022, vol. 414, p. 140176. https://doi.org/10.1016/j.electacta.2022.140176
Wannapop, S. and Somdee, A., Effect of citric acid on the synthesis of ZnWO4/ZnO nanorods for photoelectrochemical water splitting, Inorg. Chem. Commun., 2020, vol. 115, p. 107857. https://doi.org/10.1016/j.inoche.2020.107857
Navarro-Gázquez, P.J., Blasco-Tamarit, E., Muñoz-Portero, M.J., Solsona, B., Fernández-Domene, R.M., Sánchez-Tovar, R., and García-Antón, J., Influence of Zn(NO3)2 concentration during the ZnO electrodeposition on TiO2 nanosponges used in photoelectrochemical applications, Ceram. Int., 2022, vol. 48, p. 14460. https://doi.org/10.1016/j.ceramint.2022.01.339
Chen, Y., Wang, L., Gao, R., Zhang, Y.-C., Pan, L., Huang, C., Liu, K., Chang, X.-Y., Zhang, X., and Zou, J.-J., Polarization-Enhanced direct Z-scheme ZnO-WO3–x nanorod arrays for efficient piezoelectric-photoelectrochemical Water splitting, Appl. Catal. B: Environ., 2019, vol. 259, p. 118079. https://doi.org/10.1016/j.apcatb.2019.118079
Uchiyama, H., Nagao, R., and Kozuka, H., Photoelectrochemical properties of ZnO–SnO2 films prepared by sol–gel method, J. Alloys Compd., 2013, vol. 554, p. 122. https://doi.org/10.1016/j.jallcom.2012.11.196
He, G., Mi, Y., Wang, D., Zhang, B., Zheng, D., Bai, Y., and Shi, Z., Synthesis Methods and Applications of Semiconductor Material ZnWO4 with Multifunctions and Multiconstructions, Energy Technol., 2021, vol. 9, p. 2100733. https://doi.org/10.1002/ente.202100733
Jaramillo-Páez, C., Navío, J.A., Puga, F., and Hidalgo, M.C., Sol-gel synthesis of ZnWO4-(ZnO) composite materials. Characterization and photocatalytic properties, J. Photochem. Photobiol. A: Chem., 2021, vol. 404, p. 112962. https://doi.org/10.1016/j.jphotochem.2020.112962
Gao, D., Li, H., Wei, P., Wang, Y., Wang, G., and Bao, X., Electrochemical synthesis of catalytic materials for energy catalysis, Chinese J. Catal., 2022, vol. 43, p. 1001. https://doi.org/10.1016/S1872-2067(21)63940-2
Kromer, M.L., Monzó, J., Lawrence, M.J., Kolodziej, A., Gossage, Z.T., Simpson, B.H., Morandi, S., Yanson, A., Rodríguez-López, J., and Rodríguez, P., High-Throughput Preparation of Metal Oxide Nanocrystals by Cathodic Corrosion and Their Use as Active Photocatalysts, Langmuir, 2017, vol. 33, p. 13295. https://doi.org/10.1021/acs.langmuir.7b02465
Ulyankina, A., Molodtsova, T., Gorshenkov, M., Leontyev, I., Zhigunov, D., Konstantinova, E., Lastovina, T., Tolasz, J., Henych, J., Licciardello, N., Cuniberti, G., and Smirnova, N., Photocatalytic degradation of ciprofloxacin in water at nano-ZnO prepared by pulse alternating current electrochemical synthesis, J. Water Process. Eng., 2021, vol. 40, p. 101809. https://doi.org/10.1016/j.jwpe.2020.101809
Mediouni, N., Guillard, C., Dappozze, F., Khrouz, L., Parola, S., Colbeau-Justin, C., Amara, A.B.H., Rhaiem, H.B., Jaffrezic-Renault, N., and Namour, P., Impact of structural defects on the photocatalytic properties of ZnO, J. Hazard. Mater. Adv., 2022, vol. 6, p. 100081. https://doi.org/10.1016/j.hazadv.2022.100081
Gonçalves, R.F., Longo, E., Marques, A.P.A., Silva, M.D.P., Cavalcante, L.S., Nogueira, I.C., Pinatti, I.M., Pereira, P.F.S., and Godinho, M.J., Structural investigation and photoluminescent properties of ZnWO4:Dy3+ nanocrystals, J. Mater. Sci. Mater. Electron., 2017, vol. 28, p. 15466. https://doi.org/10.1007/s10854-017-7434-0
Wei, Y., Wang, L., and Chen, C., Yttrium doping enhances the photoelectrochemical water splitting performance of ZnO nanorod array films, J. Alloys Compd., 2022, vol. 896, p. 163144. https://doi.org/10.1016/j.jallcom.2021.163144
Masoumi, Z., Tayebi, M., Kolaei, M., and Lee, B.-K., Improvement of surface light absorption of ZnO photoanode using a double heterojunction with α–Fe2O3/g–C3N4 composite to enhance photoelectrochemical water splitting, Appl. Surf. Sci., 2023, vol. 608, p. 154915. https://doi.org/10.1016/j.apsusc.2022.154915
Li, P., Zhao, X., Jia, C.-j., Sun, H., Sun, L., Cheng, X., Liu, L., and Fan, W., ZnWO4/BiOI heterostructures with highly efficient visible light photocatalytic activity: the case of interface lattice and energy level match, J. Mater. Chem. A, 2013, vol. 1, p. 3421. https://doi.org/10.1039/C3TA00442B
Hao, Y., Zhang, L., Zhang, Y., Zhao, L., and Zhang, B., Synthesis of pearl necklace-like ZnO–ZnWO4 heterojunctions with enhanced photocatalytic degradation of Rhodamine B, RSC Adv., 2017, vol. 7, p. 26179. https://doi.org/10.1039/C6RA28766B
Savić, T.D., Validžić, I.L., Novaković, T.B., Vuković, Z.M., and Čomor, M.I., A Synergy of ZnO and ZnWO4 in Composite Nanostructures Deduced from Optical Properties and Photocatalysis, J. Clust. Sci., 2013, vol. 24, p. 679.https://doi.org/10.1007/s10876-013-0562-7
Leeladevi, K., Arunpandian, M., Vinoth Kumar, J., Chellapandi, T., Mathumitha, G., Lee, J.-W., and Nagarajan, E.R., CoWO4 decorated ZnO nanocomposite: Efficient visible-light-activated photocatalyst for mitigation of noxious pollutants, Physica B Condens. Matter, 2022, vol. 626, p. 413493. https://doi.org/10.1016/j.physb.2021.413493
Kurenkova, A.Y., Yakovleva, A.Y., Saraev, A.A., Gerasimov, E.Y., Kozlova, E.A., and Kaichev, V.V., Copper-Modified Titania-Based Photocatalysts for the Efficient Hydrogen Production under UV and Visible Light from Aqueous Solutions of Glycerol, Nanomaterials, 2022, vol. 12, p. 3106. https://doi.org/10.3390/nano12183106
Sena, I.C., Sales, D.d.O., Andrade, T.S., Rodriguez, M., da Silva, A.C., Nogueira, F.G.E., Rodrigues, J.L., de Mesquita, J.P., and Pereira, M.C., Photoassisted chemical energy conversion into electricity using a sulfite‑iron photocatalytic fuel cell, J. Electroanal. Chem., 2021, vol. 881, p. 114940. https://doi.org/10.1016/j.jelechem.2020.114940
He, L., Yang, Z., Gong, C., Liu, H., Zhong, F., Hu, F., Zhang, Y., Wang, G., and Zhang, B., The dual-function of photoelectrochemical glucose oxidation for sensor application and solar-to-electricity production, J. Electroanal. Chem., 2021, vol. 882, p. 114912. https://doi.org/10.1016/j.jelechem.2020.114912
Yong, Z.-J., Lam, S.-M., Sin, J.-C., Zeng, H., Mohamed, A.R., and Jaffari, Z.H., Boosting sunlight-powered photocatalytic fuel cell with S-scheme Bi2WO6/ZnO nanorod array composite photoanode, Inorg. Chem. Commun., 2022, vol. 143, p. 109826. https://doi.org/10.1016/j.inoche.2022.109826
Lam, S.-M., Sin, J.-C., Lin, H., Li, H., Lim, J.W., and Zeng, H., A Z-scheme WO3 loaded-hexagonal rod-like ZnO/Zn photocatalytic fuel cell for chemical energy recuperation from food wastewater treatment, Appl. Surf. Sci., 2020, vol. 514, p. 145945. https://doi.org/10.1016/j.apsusc.2020.145945
Xie, S., Ouyang, K., and Shao, Y., A solar responsive photocatalytic fuel cell with a heterostructured ZnFe2O4/TiO2-NTs photoanode and an air-breathing cathode, Int. J. Hydrogen Energy, 2017, vol. 42, p. 29201. https://doi.org/10.1016/j.ijhydene.2017.10.059