ELECTROTRANSPOT CHARACTERISTICS OF POLYANILINE-MODIFIED CATION EXCHANGE MEMBRANES IN SOLUTIONS OF NICKEL AND CHROMIUM SULFATES AND SULFURIC ACID

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The electrotranspot and structural characteristics of the MK-40 and MF-4SK sulfocationic membranes modified with polyaniline in an electrodialysis apparatus were studied in solutions of nickel and chromium sulfates and sulfuric acid. The decrease in the conductivity of membranes and the increase in their diffusion permeability in solutions of all electrolytes after modification with polyaniline were estimated. The key effect of the charge of the counterion on the electrical conductivity of the initial and modified membranes was confirmed, and an unusual effect of reducing the electrical conductivity of the MF-4SK/PANI membrane with an increase in the concentration of a solution containing multi-charged counter-ion was found. The information on the effect of multi-charged ions on the structure of a homogeneous and heterogeneous membranes, obtained by the method of standard contact porometry, is supplemented by the estimation of transport and structural parameters of microheterogeneous model. Based on the analysis of the parameters of current-voltage curves in solutions of nickel and chromium sulfates and sulfuric acid, the prospects of using the polyaniline-modified membranes in the processes of electrodialysis treatment of acid solutions containing multi-charged ions are evaluated.

Авторлар туралы

I. Falina

Kuban State University

Email: irina_falina@mail.ru
149 Stavropolskaya st., Krasnodar, 350040 Russia

N. Loza

Kuban State University

Email: irina_falina@mail.ru
149 Stavropolskaya st., Krasnodar, 350040 Russia

N. Kononenko

Kuban State University

Email: irina_falina@mail.ru
149 Stavropolskaya st., Krasnodar, 350040 Russia

N. Kutenko

Kuban State University

Хат алмасуға жауапты Автор.
Email: irina_falina@mail.ru
149 Stavropolskaya st., Krasnodar, 350040 Russia

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