Features of Cl  K -edge XANES spectra of metal transition complexes {MCl 6 }  n –  (M = Rh, Pd, Re, Os, Ir, Pt)

A. D. Fedorenko; Федоренко А. Д.; I. P. Asanov; Асанов И. П.; T. I. Asanova; Асанова Т. И.; D. B. Vasilchenko; Васильченко Д. Б.; A. D. Nikolenko; Николенко А. Д.; P. A. Piminov; Пиминов П. А.; K. Yu. Karyukina; Карюкина К. Ю.

doi:10.31857/S0367676522701253

Features of Cl K-edge XANES spectra of metal transition complexes {MCl₆}^n– (M = Rh, Pd, Re, Os, Ir, Pt)

Авторлар: Fedorenko A.¹, Asanov I.¹, Asanova T.¹, Vasilchenko D.¹, Nikolenko A.²^,3^,4, Piminov P.³^,4, Karyukina K.³^,4
Мекемелер:
1. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
2. Federal Research Center Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences”
3. Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences
4. Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis of Siberian Branch of the Russian Academy of Sciences
Шығарылым: Том 87, № 5 (2023)
Беттер: 738-746
Бөлім: Articles
URL: https://journals.rcsi.science/0367-6765/article/view/135391
DOI: https://doi.org/10.31857/S0367676522701253
EDN: https://elibrary.ru/ABHSZL
ID: 135391

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

Cl K-edges of a set of chlorides of 4d- and 5d-transition metals {MCl₆}^n– (M = Rh, Pd, Re, Os, Ir, Pt) were obtained using the “Cosmos” station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical methods made it possible to determine the magnitude of the spin-orbit interaction (SOC) depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, as well as stretched and compressed complexes.

Авторлар туралы

A. Fedorenko

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

I. Asanov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

T. Asanova

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

D. Vasilchenko

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

A. Nikolenko

Federal Research Center Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences”; Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

P. Piminov

Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

K. Karyukina

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

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