Luminescence of Oxyfluoride Glasses Containing Yb3+–RE3+ Ions


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Abstract

The optical absorption and up-conversion luminescence of oxyfluoride glasses in the system SiO2–PbO–PbF2–CdF2 coactivated by Yb3+–RE3+ ions (where RE = Er, Tm, Ho, Dy, Pr, or Tb) are investigated. Excitation with a laser diode in the IR range (960 nm) gives intense green, blue, and red luminescence. The color characteristics of the up-conversion luminescence in the CIE 1931 system are determined. The efficiency of energy transfer from the Yb3+ to the RE3+ ions is found to be 70% for RE = Er, Tm, and Ho. The efficiency of cooperative energy transfer reaches 10% for glass with Yb–Tb ions.

About the authors

P. A. Loiko

Belorussian National Technical University, National Research Center for Optical Materials and Technologies

Email: rach_halina@mail.ru
Belarus, Minsk

G. E. Rachkovskaya

Belorussian State Technological University

Author for correspondence.
Email: rach_halina@mail.ru
Belarus, Minsk

G. B. Zakharevich

Belorussian State Technological University

Email: rach_halina@mail.ru
Belarus, Minsk

N. A. Skoptsov

Belorussian National Technical University, National Research Center for Optical Materials and Technologies

Email: rach_halina@mail.ru
Belarus, Minsk

K. V. Yumashev

Belorussian National Technical University, National Research Center for Optical Materials and Technologies

Email: rach_halina@mail.ru
Belarus, Minsk

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