Titanium in the Structure of Alkali Borosilicate Glasses


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Abstract

Vibrational spectroscopy is used to show that the effect of adding titanium to K2O–B2O3–SiO2 glasses differing by the ratio of the boron and alkali metal contents is different. This result reflects the change in the structural role of titanium in the glass and is important for evaluating the influence of titanium additions on the properties of alkali borosilicate glass in the process of improving the glassy matrix materials used for the immobilization of radwastes.

About the authors

V. E. Eremyashev

Southern Ural State University; Institute of Mineralogy, Ural Branch of the Russian Academy of Sciences

Author for correspondence.
Email: vee-zlat@mineralogy.ru
Russian Federation, Chelyabinsk; Miass, Chelyabinsk Oblast

G. G. Korinevskaya

Institute of Mineralogy, Ural Branch of the Russian Academy of Sciences

Email: vee-zlat@mineralogy.ru
Russian Federation, Miass, Chelyabinsk Oblast

S. S. Bukalov

Institute of Organometallic Compounds, Russian Academy of Sciences

Email: vee-zlat@mineralogy.ru
Russian Federation, Moscow

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