Composition of the liquid products of the supercritical fluid extraction of oil shale from the Chim-Loptyugskoe deposit


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Abstract

Data on the liquid product composition of the thermal degradation of the organic matter of an oil shale sample from the Chim-Loptyugskoe deposit in benzene under supercritical conditions in temperature ranges to 200, 200–300, and 300–400°C were acquired with the use of a set of analytical methods. It was found that the concentration of tar–asphaltene substances in the pyrolyzates decreased with temperature; in the structure of these substances, the fraction of aromatic fragments increased and the fraction of aliphatic fragments decreased. The fraction of polar compounds in the composition of oil components decreased.

About the authors

Yu. F. Patrakov

Institute of Coal, Siberian Branch

Email: azot@ipc.tsc.ru
Russian Federation, Kemerovo, 650610

E. Yu. Kovalenko

Institute of Petroleum Chemistry, Siberian Branch

Author for correspondence.
Email: azot@ipc.tsc.ru
Russian Federation, Tomsk

Ya. Yu. Mel’nikov

National Research Tomsk Polytechnic University

Email: azot@ipc.tsc.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050

T. A. Sagachenko

Institute of Petroleum Chemistry, Siberian Branch

Email: azot@ipc.tsc.ru
Russian Federation, Tomsk

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