Optical Spectra of Composite Materials Based on Molybdenum-
Containing Nanoparticles and High-Pressure Polyethylene

A. S. Fionov; Фионов А. С.; V. V. Kolesov; Колесов В. В.; V. A. Fionova; Фионова В. А.; N. A. Taratanov; Таратанов Н. А.; E. V. Golovanov; Голованов Е. В.; E. B. Dzhangurazov; Джангуразов Э. Б.; B. Z. Beshtoev; Бештоев Б. З.; A. S. Voronov; Воронов А. С.; G. Yu. Yurkov; Юрков Г. Ю.

doi:10.31857/S0207401X2311002X

Optical Spectra of Composite Materials Based on Molybdenum- Containing Nanoparticles and High-Pressure Polyethylene

Authors: Fionov A.S.¹, Kolesov V.V.¹, Fionova V.A.², Taratanov N.A.³, Golovanov E.V.¹, Dzhangurazov E.B.⁴, Beshtoev B.Z.⁴, Voronov A.S.⁵, Yurkov G.Y.⁴
Affiliations:
1. Kotelnikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences
2. Bauman Moscow State Technical University
3. Ivanovo Fire and Rescue Academy of the State Fire Service of the Ministry of Emergency Situations of Russia
4. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
5. State Scientific Center of the Russian Federation Troitsk Institute of Innovation and Thermonuclear Research
Issue: Vol 42, No 11 (2023)
Pages: 79-88
Section: Chemical physics of polymeric materials
URL: https://journals.rcsi.science/0207-401X/article/view/233221
DOI: https://doi.org/10.31857/S0207401X2311002X
EDN: https://elibrary.ru/YXPKNP
ID: 233221

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Abstract
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Abstract

Molybdenum-containing composite nanomaterials are synthesized by the thermal decomposition
of molybdenum hexacarbonyl in a solution-melt of polyethylene in mineral oil. The concentration of a metalcontaining
filler in the composite materials varied from 1 to 20 wt %. A technique for preparing film samples
for spectroscopic studies is developed, and the samples obtained are studied by UVI, IR, and Raman spectroscopy.
It is found that additional absorption bands appear in the IR range, whose intensity depends on the
concentration of molybdenum-containing nanoparticles in the composite materials. The spectral characteristics
of Raman scattering show that all samples are characterized by the stretching of the C–C bond. In the
visible light region, the spectrum of nanocomposites has a flat edge of its own absorption located in the region
of wave numbers (18–31) × 103 cm–1.

Keywords

nanocomposite, polyethylene, molybdenum, nanoparticles, functional material, optical spectra, FTIR spectra, Raman spectra

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