The Rate of Absorption by the Styrene Epoxide–P-Toluene Sulfonic
Acid Double System Depending on the Structure of the Aliphatic Tail
of the Alcohol Solvent

V. M. Solyanikova; Соляников В. М.; L. V. Petrov; Петров Л. В.

doi:10.31857/S0207401X23120129

The Rate of Absorption by the Styrene Epoxide–P-Toluene Sulfonic Acid Double System Depending on the Structure of the Aliphatic Tail of the Alcohol Solvent

Авторлар: Solyanikova V.¹, Petrov L.¹
Мекемелер:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Шығарылым: Том 42, № 12 (2023)
Беттер: 12-17
Бөлім: КИНЕТИКА И МЕХАНИЗМ ХИМИЧЕСКИХ РЕАКЦИЙ, КАТАЛИЗ
URL: https://journals.rcsi.science/0207-401X/article/view/233195
DOI: https://doi.org/10.31857/S0207401X23120129
EDN: https://elibrary.ru/JTCNJB
ID: 233195

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

Oxygen oxidation of the styrene epoxide (SE)–p-toluene sulfonic acid (TSA) double system (DS)
in solutions of three primary alcohols, 1-octanol (OCT), n-butanol (BUT), and ethanol (ET), is studied. The
corresponding concentration expressions of oxidation rates are as follows: VOCT = k [SE]0 [TSA]1, VBUT = k
[SE]0 [TSA]0.63, and VET = k [SE]0 [TSA]0.7 at [SE] [TSA]. The proximity of the oxidation activation energies
in three alcohols contrasts with the difference in the oxidation rates: the oxidation rate in ET is three
times the rate in n-butanol and thirty times the oxidation rate in 1-octanol.

Негізгі сөздер

Oxidation by molecular oxygen, catalysis, styrene epoxide, p-toluene sulfonic acid, 1-octanol, nbutanol, ethanol

Авторлар туралы

V. Solyanikova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: plv@icp.ac.ru
Chernogolovka, Russia

L. Petrov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: plv@icp.ac.ru
Chernogolovka, Russia

Әдебиет тізімі

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