Синтез гидроксиапатита, замещенного ионами РЗЭ элементов (Lа 3+ , Cе 3+ )

О. А. Голованова; Голованова О. А.

doi:10.31857/S0132665124040064

Синтез гидроксиапатита, замещенного ионами РЗЭ элементов (Lа³⁺, Cе³⁺)

Authors: Голованова О.А.¹
Affiliations:
1. Омский государственный университет им. Ф.М. Достоевского
Issue: Vol 50, No 4 (2024)
Pages: 414-426
Section: Articles
URL: https://journals.rcsi.science/0132-6651/article/view/279965
DOI: https://doi.org/10.31857/S0132665124040064
EDN: https://elibrary.ru/QBSYOF
ID: 279965

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Abstract

Осуществлен синтез замещенных апатитов с варьированием содержания ионов La³⁺и Ce^3+. Методами РФА и ИК-спектроскопией доказано образование замещенного гидроксиапатита (La-ГА, Ce-ГА). Показано изменение параметров кристаллических решеток синтезированных фаз, что свидетельствует о замещении ионов Ca²⁺на ионы РЗЭ в структуре гидроксиапатита. Методом АЭС с ИСП доказано присутствие ионов РЗЭ в твердых фазах. При изучении резорбции синтезированных образцов выявлено, что катион-замещенные гидроксиапатиты менее растворимы, чем не допированный ГА.

Keywords

лантан и церий, гидроксиапатит, отношения Ca/P, растворимость

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About the authors

О. А. Голованова

Омский государственный университет им. Ф.М. Достоевского

Author for correspondence.
Email: golovanoa2000@mail.ru
Russian Federation, 644077, Омская область, г. Омск, пр. Мира, 55 а

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2. Fig. 1. Diffraction patterns of synthesized hydroxyapatite samples: fragment of the X-ray diffraction pattern of hydroxyapatite with the indication of the 2θ reflection angles and the corresponding hkl indices (a), with the addition of La3+ ions (б), with the addition of Ce3+ ions (в), line X-ray diffraction pattern of hydroxyapatite (г).

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3. Fig. 2. IR spectra of synthesized hydroxyapatite samples: with the addition of La3+ ions (a), with the addition of Ce3+ ions (б).

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4. Fig. 3. Micrographs of GA: without addition of REE ions (a); 2% La3+ (б); 5% La3+ (в), 2% Ce3+ (г); 5% Ce3+ (д).

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5. Fig. 4. Kinetic curves of dissolution of hydroxyapatite samples in acetate buffer: with the addition of La3+ ions (a); with the addition of Ce3+ ions (б).