Anisotropy of Thermal Expansion of Oxoborate Warwickite

Ya. P. Biryukov; Бирюков Я. П.; R S. Bubnova; Бубнова Р. С.; S. K. Filatov; Филатов С. К.

doi:10.31857/S0132665123600231

Anisotropy of Thermal Expansion of Oxoborate Warwickite

Authors: Biryukov Y.P.¹, Bubnova RS.¹, Filatov S.K.²
Affiliations:
1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia
2. Saint Petersburg State University
Issue: Vol 49, No 5 (2023)
Pages: 538-545
Section: Articles
URL: https://journals.rcsi.science/0132-6651/article/view/139347
DOI: https://doi.org/10.31857/S0132665123600231
EDN: https://elibrary.ru/OMVJEZ
ID: 139347

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Abstract
About the authors
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Abstract

In this paper, the transition metal oxoborate warwickite (Fe2+,Mg)Fe3+(BO3)O is studied for the first time by low- and high-temperature X-ray diffraction in the temperature range from 93 to 513 K. The sharply anisotropic nature of its thermal expansion is revealed. A structural interpretation of the expansion mechanism is given both in terms of the contribution of cationic and oxocentered polyhedra.

Keywords

oxoborate, warwickite, phase transitions, crystal structure, thermal expansion, thermal X-ray radiography

About the authors

Ya. P. Biryukov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Email: y.p.biryukov@gmail.com
Россия, 199034, наб. Макарова, 2, Санкт-Петербург

R S. Bubnova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Email: rimma_bubnova@mail.ru
Россия, 199034, Санкт-Петербург, наб. Макарова, 2

S. K. Filatov

Saint Petersburg State University

Author for correspondence.
Email: filatov.stanislav@gmail.com
Russia, Saint Petersburg

References

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