Email this article Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2
- Authors: Yukhno V.A.1, Charkin D.O.2,3, Volkov S.N.1,3, Manelis L.S.2,3, Gosteva A.N.4, Aksenov S.M.3, Bubnova RS.1
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Affiliations:
- Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia
- Department of Chemistry, Moscow State University, 119991, Moscow, Russia
- Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
- Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
- Issue: Vol 49, No 5 (2023)
- Pages: 532-537
- Section: Articles
- URL: https://journals.rcsi.science/0132-6651/article/view/139344
- DOI: https://doi.org/10.31857/S0132665123600255
- EDN: https://elibrary.ru/YVZOXU
- ID: 139344
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Abstract
Crystals of a novel hybrid organo-inorganic borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2 (1), were obtained from aqueous solutions and characterized by single-crystal X-ray diffraction and IR spectroscopy. 1 is triclinic (a = 10.1567(4), b = 11.9941(6), c = 17.1893(9) Å, α = 75.280(4), β = 79.406(4), γ = 88.531(4)°, V = 1990.270369 Å3, SG P-1; R1 = 0.058). Its structure contains [K(C10H20O5)2]+ groups which behave as “hydrophobic” templates for the inorganic part comprised of B5O6(OH)4 anions and neutral B(OH)3 molecules.
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About the authors
V. A. Yukhno
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia
Email: yukhno.valentina@gmail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, 2
D. O. Charkin
Department of Chemistry, Moscow State University, 119991, Moscow, Russia; Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
Email: yukhno.valentina@gmail.com
Россия, 119991, Москва, Ленинские горы, д. 1, стр. 3; Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14
S. N. Volkov
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia; Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
Email: yukhno.valentina@gmail.com
Россия, 199034, Санкт-Петербург, наб. Макарова, 2; Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14
L. S. Manelis
Department of Chemistry, Moscow State University, 119991, Moscow, Russia; Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
Email: yukhno.valentina@gmail.com
Россия, 119991, Москва, Ленинские горы, д. 1, стр. 3; Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14
A. N. Gosteva
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
Email: yukhno.valentina@gmail.com
Россия, 184209, Мурманская обл.,, Апатиты, мкр. Академгородок, д. 26А
S. M. Aksenov
Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia
Email: yukhno.valentina@gmail.com
Россия, 184209, Мурманская обл, Апатиты, ул. Ферсмана, 14
R S. Bubnova
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia
Author for correspondence.
Email: rimma_bubnova@mail.ru
Россия, 199034, Санкт-Петербург, наб. Макарова, 2
References
- Becker P. Borate materials in nonlinear optics //Advanced Materials. 1998. V. 10. № 13. P. 979–992.
- Chen C., Sasaki T., Li R., Wu Y., Lin Z., Mori Y., Kaneda Y. Nonlinear optical borate crystals: Principals and applications // John Wiley & Sons, 2012.
- Mutailipu M., Pan S. Emergent deep-ultraviolet nonlinear optical candidates // Angewandte Chemie International Edition. 2020. V. 59. № 46. P. 20302–20317.
- Mutailipu M., Poeppelmeier K.R., Pan S. Borates: a rich source for optical materials // Chemical Reviews. 2020. V. 121. № 3. P. 1130–1202.
- Sasaki T., Mori Y., Yoshimura M., Yap Y.K., Kamimura T. Recent development of nonlinear optical borate crystals: key materials for generation of visible and UV light // Materials Science and Engineering: R: Reports. 2000. V. 30. № 1–2. P. 1–54.
- Steed J.W. First-and second-sphere coordination chemistry of alkali metal crown ether complexes // Coordination Chemistry Reviews. 2001. V. 215. № 1. P. 171–221.
- Fabbrizzi L. Cryptands and cryptates // World Scientific: Hackensack. NJ. 2018. P. 1–9.
- Cole M.L., Jones C., Junk P.C. Ether and crown ether adduct complexes of sodium and potassium cyclopentadienide and methylcyclopentadienide-molecular structures of [Na (dme) Cp]∞,[K (dme) 0.5 Cp]∞,[Na (15-crown-5) Cp],[Na (18-crown-6) Cp Me] and the “naked Cp−” complex [K (15-crown-5) 2][Cp] // Dalton Transactions. 2002. № 6. P. 896–905.
- Rigaku Oxford Diffraction, CrysAlisPRO Software System, Version 1.171.41.104a. 2021. Rigaku Corporation, Oxford, UK.
- Palatinus L., Chapuis G. SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions // J. Appl. Cryst. 2007. V. 40. P. 786.
- Petříček V., Dušek M., Palatinus L. Crystallographic Computing System JANA2006: General Features // Z. Kristallogr. Cryst. Mater. 2014. V. 229 (5). P. 345–352.
- Bubnova R.S., Filatov S.K. High-temperature borate crystal chemistry // Z. Kristallogr. Cryst. Mater. 2013. V. 228. № 9. P. 395–428.
- Burns P.C., Grice J.D., Hawthorne F.C. Borate minerals; I. Polyhedral clusters and fundamental building blocks // The Canadian Mineralogist. 1995. V. 33. № 5. P. 1131–1151.
- Hawthorne F.C., Burns P.C., Grice J.D. The crystal chemistry of boron // Reviews in Mineralogy and Geochemistry. 1996. V. 33. № 1. P. 41–115.
- Ashmore J.P., Petch H.E. Hydrogen positions in potassium pentaborate tetrahydrate as determined by neutron diffraction // Canadian Journal of Physics. 1970. V. 48. № 9. P. 1091–1097.
- Penin N., Seguin L., Gerand B., Touboul M., Nowogrocki G. Crystal structure of a new form of Cs[B5O6(OH)4]⋅2H2O and thermal behavior of M[B5O6(OH)4]⋅2H2O (M= Cs, Rb, Tl) // Journal of alloys and compounds. 2002. V. 334. № 1–2. P. 97–109.
- Behm H. Structure determination on a twinned crystal of cesium pentaborate tetrahydrate, Cs [B5O6(OH)4]⋅2H2O // Acta Crystallographica Section C: Crystal Structure Communications. 1984. V. 40. № 7. P. 1114–1116.
- Behm H. Rubidium pentaborate tetrahydrate, Rb [B5O6(OH)4]⋅2H2O //Acta Crystallographica Section C: Crystal Structure Communications. 1984. V. 40. № 2. P. 217–220.
- Wang S., Alekseev E.V., Diwu J., Casey W.H., Phillips B.L., Depmeier W., Albrecht-Schmitt T.E. NDTB-1: A Supertetrahedral Cationic Framework That Removes Tc from Solution // Angewandte Chemie. 2010. V. 122. № 6. P. 1075–1078.
